普鲁士蓝类似物在水系锌离子电池中的应用研究
Research on the Application of Prussian Blue Analogues in Aqueous Zinc-Ion Batteries
摘要: 水系锌离子电池凭借高安全性、低成本与环境友好等优势,在可持续能源存储领域展现出巨大的应用潜力。其中,普鲁士蓝类似物因具有独特的开放式骨架结构、可调控的化学组成以及优异的电化学性能,作为正极材料受到广泛关注。本文综述了普鲁士蓝类似物在水系锌离子电池中的研究进展,涵盖材料结构特性、改性策略,及界面工程等方面,并探讨了当前面临的挑战、未来的研究重点与发展方向。
Abstract: Aqueous zinc-ion batteries have demonstrated significant application potential in the field of sustainable energy storage, owing to their advantages of high safety, low cost, and environmental friendliness. Among various candidate materials, Prussian blue analogues have garnered widespread attention as cathode materials due to their unique open-framework structure, tunable chemical composition, and excellent electrochemical performance. This review summarizes the recent research progress on Prussian blue analogues for aqueous zinc-ion batteries, covering aspects of their material structural characteristics, modification strategies, and interface engineering. Furthermore, the current challenges and future research priorities and development directions are discussed.
文章引用:王涛涛, 叶盼盼, 任凌云. 普鲁士蓝类似物在水系锌离子电池中的应用研究[J]. 材料化学前沿, 2025, 13(4): 447-454. https://doi.org/10.12677/amc.2025.134046

参考文献

[1] Augustyn, V., Simon, P. and Dunn, B. (2014) Pseudocapacitive Oxide Materials for High-Rate Electrochemical Energy Storage. Energy & Environmental Science, 7, 1597-1614. [Google Scholar] [CrossRef
[2] Chu, S. and Majumdar, A. (2012) Opportunities and Challenges for a Sustainable Energy Future. Nature, 488, 294-303. [Google Scholar] [CrossRef] [PubMed]
[3] Zhao, R., Elzatahry, A., Chao, D. and Zhao, D. (2022) Making MXenes More Energetic in Aqueous Battery. Matter, 5, 8-10. [Google Scholar] [CrossRef
[4] Song, M., Tan, H., Chao, D. and Fan, H.J. (2018) Recent Advances in Zn‐Ion Batteries. Advanced Functional Materials, 28, Article ID: 1802564. [Google Scholar] [CrossRef
[5] Dunn, B., Kamath, H. and Tarascon, J. (2011) Electrical Energy Storage for the Grid: A Battery of Choices. Science, 334, 928-935. [Google Scholar] [CrossRef] [PubMed]
[6] Yi, J., Guo, S., He, P. and Zhou, H. (2017) Status and Prospects of Polymer Electrolytes for Solid-State Li-O2(Air) Batteries. Energy & Environmental Science, 10, 860-884. [Google Scholar] [CrossRef
[7] Li, Q., Liu, Y., Guo, S. and Zhou, H. (2017) Solar Energy Storage in the Rechargeable Batteries. Nano Today, 16, 46-60. [Google Scholar] [CrossRef
[8] Simon, P., Gogotsi, Y. and Dunn, B. (2014) Where Do Batteries End and Supercapacitors Begin? Science, 343, 1210-1211. [Google Scholar] [CrossRef] [PubMed]
[9] Chao, D., DeBlock, R., Lai, C., Wei, Q., Dunn, B. and Fan, H.J. (2021) Amorphous VO2: A Pseudocapacitive Platform for High‐Rate Symmetric Batteries. Advanced Materials, 33, e2103736. [Google Scholar] [CrossRef] [PubMed]
[10] Pan, Z., Yang, J., Li, L., Gao, X., Kang, L., Zhang, Y., et al. (2020) All-in-One Stretchable Coaxial-Fiber Strain Sensor Integrated with High-Performing Supercapacitor. Energy Storage Materials, 25, 124-130. [Google Scholar] [CrossRef
[11] Schmidt, O., Hawkes, A., Gambhir, A. and Staffell, I. (2017) The Future Cost of Electrical Energy Storage Based on Experience Rates. Nature Energy, 2, Article No. 17110. [Google Scholar] [CrossRef
[12] Du, W., Ang, E.H., Yang, Y., Zhang, Y., Ye, M. and Li, C.C. (2020) Challenges in the Material and Structural Design of Zinc Anode Towards High-Performance Aqueous Zinc-Ion Batteries. Energy & Environmental Science, 13, 3330-3360. [Google Scholar] [CrossRef
[13] Liu, D., Mai, Y., Chen, S., Liu, S., Ang, E.H., Ye, M., et al. (2021) A 1D-3D Interconnected δ-MnO2 Nanowires Network as High-Performance and High Energy Efficiency Cathode Material for Aqueous Zinc-Ion Batteries. Electrochimica Acta, 370, Article ID: 137740. [Google Scholar] [CrossRef
[14] Islam, S., Alfaruqi, M.H., Putro, D.Y., Park, S., Kim, S., Lee, S., et al. (2021) In Situ Oriented Mn Deficient ZnMn2O4@C Nanoarchitecture for Durable Rechargeable Aqueous Zinc‐Ion Batteries. Advanced Science, 8, Article ID: 2002636. [Google Scholar] [CrossRef] [PubMed]
[15] Tan, Q., Li, X., Zhang, B., Chen, X., Tian, Y., Wan, H., et al. (2020) Valence Engineering via in Situ Carbon Reduction on Octahedron Sites Mn3O4 for Ultra‐Long Cycle Life Aqueous Zn‐Ion Battery. Advanced Energy Materials, 10, Article ID: 2001050. [Google Scholar] [CrossRef
[16] Cao, L., Lu, D., Zhong, D. and Lu, T. (2020) Prussian Blue Analogues and Their Derived Nanomaterials for Electrocatalytic Water Splitting. Coordination Chemistry Reviews, 407, Article ID: 213156. [Google Scholar] [CrossRef
[17] Liu, W., Zhang, X., Huang, Y., Jiang, B., Chang, Z., Xu, C., et al. (2021) β-MnO2 with Proton Conversion Mechanism in Rechargeable Zinc Ion Battery. Journal of Energy Chemistry, 56, 365-373. [Google Scholar] [CrossRef
[18] Yang, H., Zhou, W., Chen, D., Liu, J., Yuan, Z., Lu, M., et al. (2022) The Origin of Capacity Fluctuation and Rescue of Dead Mn-Based Zn-Ion Batteries: A Mn-Based Competitive Capacity Evolution Protocol. Energy & Environmental Science, 15, 1106-1118. [Google Scholar] [CrossRef
[19] Jiao, T., Yang, Q., Wu, S., Wang, Z., Chen, D., Shen, D., et al. (2019) Binder-Free Hierarchical VS2 Electrodes for High-Performance Aqueous Zn Ion Batteries Towards Commercial Level Mass Loading. Journal of Materials Chemistry A, 7, 16330-16338. [Google Scholar] [CrossRef
[20] Ding, J., Gao, H., Zhao, K., Zheng, H., Zhang, H., Han, L., et al. (2021) In-Situ Electrochemical Conversion of Vanadium Dioxide for Enhanced Zinc-Ion Storage with Large Voltage Range. Journal of Power Sources, 487, Article ID: 229369. [Google Scholar] [CrossRef
[21] Li, W., Han, C., Gu, Q., Chou, S., Wang, J., Liu, H., et al. (2020) Electron Delocalization and Dissolution-Restraint in Vanadium Oxide Superlattices to Boost Electrochemical Performance of Aqueous Zinc‐ion Batteries. Advanced Energy Materials, 10, Article ID: 2001852. [Google Scholar] [CrossRef
[22] Jiang, H., Zhang, Y., Pan, Z., Xu, L., Zheng, J., Gao, Z., et al. (2020) NH4V3O8∙0.5H2O Nanobelts with Intercalated Water Molecules as a High Performance Zinc Ion Battery Cathode. Materials Chemistry Frontiers, 4, 1434-1443. [Google Scholar] [CrossRef
[23] Li, X., Ma, L., Zhao, Y., Yang, Q., Wang, D., Huang, Z., et al. (2019) Hydrated Hybrid Vanadium Oxide Nanowires as the Superior Cathode for Aqueous Zn Battery. Materials Today Energy, 14, Article ID: 100361. [Google Scholar] [CrossRef
[24] Zhang, S., Long, S., Li, H. and Xu, Q. (2020) A High-Capacity Organic Cathode Based on Active N Atoms for Aqueous Zinc-Ion Batteries. Chemical Engineering Journal, 400, Article ID: 125898. [Google Scholar] [CrossRef
[25] Jiang, B., Huang, T., Yang, P., Xi, X., Su, Y., Liu, R., et al. (2021) Solution-Processed Perylene Diimide-Ethylene Diamine Cathodes for Aqueous Zinc Ion Batteries. Journal of Colloid and Interface Science, 598, 36-44. [Google Scholar] [CrossRef] [PubMed]
[26] Zhao, L., Zhao, Y., Wu, Y., Wang, P., Liu, Z., Zhang, Q., et al. (2025) Everything in Aqueous Zinc-Ion Batteries May Be Prussian Blue Analogues: From Cathode Materials to Electrolyte Additives Applications. Energy Storage Materials, 78, Article ID: 104299. [Google Scholar] [CrossRef
[27] Wang, B., Han, Y., Wang, X., Bahlawane, N., Pan, H., Yan, M., et al. (2018) Prussian Blue Analogs for Rechargeable Batteries. iScience, 3, 110-133. [Google Scholar] [CrossRef] [PubMed]
[28] Qin, M., Ren, W., Jiang, R., Li, Q., Yao, X., Wang, S., et al. (2021) Highly Crystallized Prussian Blue with Enhanced Kinetics for Highly Efficient Sodium Storage. ACS Applied Materials & Interfaces, 13, 3999-4007. [Google Scholar] [CrossRef] [PubMed]
[29] Shu, W., Huang, M., Geng, L., Qiao, F. and Wang, X. (2023) Highly Crystalline Prussian Blue for Kinetics Enhanced Potassium Storage. Small, 19, Article ID: 2207080. [Google Scholar] [CrossRef] [PubMed]
[30] Qi, Y., Li, F., Sheng, H., Zhang, H., Yuan, J., Ma, L., et al. (2024) Seed-Assisted Reversible Dissolution/Deposition of MnO2 for Long‐Cyclic and Green Aqueous Zinc‐Ion Batteries. Small, 20, Article ID: 2404312. [Google Scholar] [CrossRef] [PubMed]
[31] Syed, W.A., Kakarla, A.K., Bandi, H., Shanthappa, R. and Yu, J.S. (2024) Copper Substituted Manganese Prussian Blue Analogue Composite Nanostructures for Efficient Aqueous Zinc-Ion Batteries. Journal of Energy Storage, 99, Article ID: 113325. [Google Scholar] [CrossRef
[32] Xue, Y., Zhou, H., Suo, X., Tao, J., Zhang, C., Ji, Z., et al. (2024) Polyaniline-Modified Amorphous Tin-Based Prussian Blue Analogue as Cathodes for Long-Life Aqueous Zinc Ion Batteries. Journal of Energy Storage, 98, Article ID: 113140. [Google Scholar] [CrossRef
[33] Yan, S., Zuo, Y., He, B., Tian, H., Meng, T., Zhang, H., et al. (2025) An Activated Prussian Blue Interphase Enhancing H+ Storage of MnO2 Cathode for Aqueous Zinc Ion Battery. Journal of Alloys and Compounds, 1036, Article ID: 181877. [Google Scholar] [CrossRef