Fe3O4/Ni复合材料用于增强析氧催化反应
Fe3O4/Ni Composite for Enhanced Oxygen Evolution Reaction
DOI: 10.12677/ms.2025.1511214, PDF,    科研立项经费支持
作者: 曹纪铭, 任一臣, 吕晓丁：塔里木大学化学化工学院，新疆 阿拉尔；张京京, 陈亚辉*：塔里木大学化学化工学院，新疆 阿拉尔；新疆生产建设兵团南疆化学工程重点实验室，新疆 阿拉尔
关键词: 电催化水分解；析氧反应；Fe3O4/Ni催化剂；Electrocatalytic Water Splitting； Oxygen Evolution Reaction； Fe3O4/Ni Catalyst
摘要: 开发先进的非贵金属析氧反应(OER)催化剂对实际电解水至关重要，而催化剂优化对于调控OER反应动力学、保证长期稳定性又起决定性作用。本研究采用水热法与热解法相结合的策略，成功制备了Fe3O4/Ni非贵金属复合催化剂，以提升OER性能。在1 M KOH电解液中测试显示：Fe3O4/Ni催化剂在10 mA∙cm−2电流密度下的过电位仅为242 mV，塔菲尔斜率低至61.04 mV∙dec−1，且具备优异的循环稳定性，综合性能显著优于单一的Ni与Fe3O4催化剂。本研究为高效非贵金属OER催化剂的设计提供了有效策略。
Abstract: Developing advanced non-noble metal catalysts for the oxygen evolution reaction (OER) is of great significance to practical water electrolysis, and material optimization plays a decisive role in regulating OER reaction kinetics and ensuring the long-term stability of catalysts. In this study, a strategy combining hydrothermal method and pyrolysis method was adopted to successfully synthesize the Fe3O4/Ni composite non-noble metal catalyst for enhancing OER performance. Tests in 1 M KOH electrolyte showed that the catalyst exhibited an overpotential of only 242 mV at a current density of 10 mA∙cm−2, a Tafel slope as low as 61.04 mV∙dec⁻¹, and excellent cyclic stability. Its comprehensive performance was significantly superior to that of pure Ni and single Fe3O4 catalysts. This study provides an effective strategy for the design of high-efficiency non-noble metal OER catalysts.
文章引用：曹纪铭, 任一臣, 吕晓丁, 张京京, 陈亚辉. Fe3O4/Ni复合材料用于增强析氧催化反应[J]. 材料科学, 2025, 15(11): 2016-2023. https://doi.org/10.12677/ms.2025.1511214

参考文献

[1] Luo, J., Wang, X., Gu, Y., Wang, D., Wang, S., Li, W., et al. (2022) Constructing Hollow Nanocages of Co3O4-CoMoO4 Heterostructure for Efficient Electrocatalytic Oxygen Evolution Reaction. Applied Surface Science, 606, Article ID: 154562. [Google Scholar] [CrossRef] 
[2] Zheng, Y., Tang, P., Xu, X. and Sang, X. (2020) POM Derived UOR and HER Bifunctional NiS/MoS2 Composite for Overall Water Splitting. Journal of Solid State Chemistry, 292, Article ID: 121644. [Google Scholar] [CrossRef] 
[3] Poudel, M.B., Logeshwaran, N., Kim, A.R., S.C., K., Vijayapradeep, S. and Yoo, D.J. (2023) Integrated Core-Shell Assembly of Ni3S2 Nanowires and CoMoP Nanosheets as Highly Efficient Bifunctional Electrocatalysts for Overall Water Splitting. Journal of Alloys and Compounds, 960, Article ID: 170678. [Google Scholar] [CrossRef] 
[4] Jiang, J., Li, F., Su, H., Gao, Y., Li, N. and Ge, L. (2022) Flower-Like NiCo2S4/NiFeP/NF Composite Material as an Effective Electrocatalyst with High Overall Water Splitting Performance. Chinese Chemical Letters, 33, 4367-4374. [Google Scholar] [CrossRef] 
[5] Wang, X., Wang, L., Liu, Y., Devasenathipathy, R., Liu, L., Huang, Q., et al. (2024) Boosting the Oxygen Evolution Reaction via the Reconstruction of an M(OH)x/Fe3O4 Catalyst. Inorganic Chemistry Frontiers, 11, 6333-6342. [Google Scholar] [CrossRef] 
[6] Xu, W., Zhong, W., Yang, C., Zhao, R., Wu, J., Li, X., et al. (2022) Tailoring Interfacial Electron Redistribution of Ni/Fe3O4 Electrocatalysts for Superior Overall Water Splitting. Journal of Energy Chemistry, 73, 330-338. [Google Scholar] [CrossRef] 
[7] Cartagena, S. and Calderón, J.A. (2022) Corrosion of Non-Noble Metal-Based Catalysts during Oxygen Evolution Reaction under on/off Operation. Corrosion Science, 205, Article ID: 110437. [Google Scholar] [CrossRef] 
[8] Ji, X., Zhang, Y., Ma, Z. and Qiu, Y. (2020) Oxygen Vacancy‐rich Ni/NiO@NC Nanosheets with Schottky Heterointerface for Efficient Urea Oxidation Reaction. ChemSusChem, 13, 5004-5014. [Google Scholar] [CrossRef] [PubMed]
[9] Li, C., Bao, A., Yang, C., Liu, G., Chen, X., Li, M., et al. (2023) Multi-Interface Engineering of NiS/Ni3S2/Fe3O4 Nanoarchitectures for Use as High-Efficiency Electrocatalysts toward the Oxygen Evolution Reaction. Inorganic Chemistry Frontiers, 10, 6664-6673. [Google Scholar] [CrossRef] 
[10] Xie, Y., Wang, X., Tang, K., Li, Q. and Yan, C. (2018) Blending Fe3O4 into a Ni/NiO Composite for Efficient and Stable Bifunctional Electrocatalyst. Electrochimica Acta, 264, 225-232. [Google Scholar] [CrossRef] 
[11] Luo, F., Pan, S., Xie, Y., Li, C., Yu, Y. and Yang, Z. (2024) Atomically Dispersed Ni Electrocatalyst for Superior Urea-Assisted Water Splitting. Journal of Energy Chemistry, 90, 1-6. [Google Scholar] [CrossRef] 
[12] Cao, W., Zhao, R., Liu, G., Wu, L. and Li, J. (2023) Three-Dimensional Ordered Macroporous Design of Heterogeneous Nickel-Iron Phosphide as Bifunctional Electrocatalyst for Enhanced Overall Water Splitting. Applied Surface Science, 607, Article ID: 154905. [Google Scholar] [CrossRef] 
[13] Zhu, J., Zhang, Q., Zhao, P., Chen, L., Yang, S., Yan, Q., et al. (2022) NiFe2O4@Co3O4 Heterostructure with Abundant Oxygen Vacancies as a Bifunctional Electrocatalyst for Overall Water Splitting. Journal of Alloys and Compounds, 918, Article ID: 165705. [Google Scholar] [CrossRef] 
[14] Garain, S., Dang Van, C., Choi, S., Nguyen Dang, T., Ager, J.W., Nam, K.T., et al. (2022) Hierarchical Thiospinel NiCo2S4/Polyaniline Hybrid Nanostructures as a Bifunctional Electrocatalyst for Highly Efficient and Durable Overall Water Splitting. Advanced Materials Interfaces, 9, Article ID: 2200649. [Google Scholar] [CrossRef] 
[15] Li, X., Xiao, L., Zhou, L., Xu, Q., Weng, J., Xu, J., et al. (2020) Adaptive Bifunctional Electrocatalyst of Amorphous CoFe Oxide @ 2D Black Phosphorus for Overall Water Splitting. Angewandte Chemie International Edition, 59, 21106-21113. [Google Scholar] [CrossRef] [PubMed]
[16] Mu, Y., Zhang, Y., Feng, Z., Dong, X., Jing, X., Pei, X., et al. (2023) Bifunctional Electrocatalyst Junction Engineering: Cop Nanoparticles In-Situ Anchored on CO3(Si2O5)2(OH)2 Nanosheets for Highly Efficient Water Splitting. Chemical Engineering Journal, 460, Article ID: 141709. [Google Scholar] [CrossRef] 
[17] Yang, H., Zhou, Z., Yu, H., Wen, H., Yang, R., Peng, S., et al. (2023) Alkali Treatment of Layered Double Hydroxide Nanosheets as Highly Efficient Bifunctional Electrocatalysts for Overall Water Splitting. Journal of Colloid and Interface Science, 636, 11-20. [Google Scholar] [CrossRef] [PubMed]
[18] Khan, J., Liu, H., Xiao, J., Zhu, Y., Hayat, A., Ullah, H., et al. (2023) Synthesis of Heteroatom Incorporated Porous Carbon Encapsulated Fe-Doped Co9S8 as an Efficient Bifunctional Electrocatalyst for Overall Water Splitting. Journal of Physics and Chemistry of Solids, 175, Article ID: 111220. [Google Scholar] [CrossRef] 
[19] Yang, X., Wu, Z., Xing, Z., Yang, C., Wang, W., Yan, R., et al. (2023) IrPd Nanoalloy‐Structured Bifunctional Electrocatalyst for Efficient and pH‐Universal Water Splitting. Small, 19, Article ID: 2208261. [Google Scholar] [CrossRef] [PubMed]
[20] Xiong, J., Cao, Z., Wang, H., Ban, D., Zhou, Z., Li, Y., et al. (2022) CoS2/MoS2 Hollow Heterostructure as High‐Efficiency Bifunctional Electrocatalyst for Overall Water Splitting. ChemistrySelect, 7, e202202700. [Google Scholar] [CrossRef] 
[21] Wang, Z., Pan, D., Chen, K., Yin, X., Wang, J., Cai, P., et al. (2023) Palladium Modified FeCoS2 Nanosheet Arrays on Ni Foam as Bifunctional Electrodes for Overall Alkaline Water Splitting. ChemistrySelect, 8, e202204456. [Google Scholar] [CrossRef] 
[22] Li, W., Feng, B., Yi, L., Li, J. and Hu, W. (2020) Highly Efficient Alkaline Water Splitting with Ru‐Doped Co-V Layered Double Hydroxide Nanosheets as a Bifunctional Electrocatalyst. ChemSusChem, 14, 730-737. [Google Scholar] [CrossRef] [PubMed]
[23] Im, S.W., Ahn, H., Park, E.S., Nam, K.T. and Lim, S.Y. (2021) Electrochemically Activated NiFeOxHy for Enhanced Oxygen Evolution. ACS Applied Energy Materials, 4, 595-601. [Google Scholar] [CrossRef] 
[24] Zou, C., Guo, X., Wang, F., Tian, R., Hou, Y., Liu, F., et al. (2022) Macroporous Ni-Fe Hydroxide Bifunctional Catalyst for Efficient Alkaline Water Splitting. Journal of Sol-Gel Science and Technology, 103, 505-514. [Google Scholar] [CrossRef] 
[25] Zhang, Y., Peng, A., Wu, Q., Shan, Y., Wei, Y., Zhou, Y., et al. (2025) Adjust Adsorption Capacity and Charge Redistribution by S-Anion Effect in Ni2Fe1S4 Nanowires for OER in Alkaline. Journal of Alloys and Compounds, 1040, Article ID: 183631. [Google Scholar] [CrossRef] 
[26] Kang, J., Yan, F., Li, C., Qi, L., Geng, B., Wang, Y., et al. (2020) NiFe2O4 Hollow Nanoparticles of Small Sizes on Carbon Nanotubes for Oxygen Evolution. Catalysis Science & Technology, 10, 6970-6976. [Google Scholar] [CrossRef] 
[27] Cossar, E., Agarwal, K., Nguyen, V.B., Safari, R., Botton, G.A. and Baranova, E.A. (2021) Highly Active Nickel-Iron Nanoparticles with and without Ceria for the Oxygen Evolution Reaction. Electrocatalysis, 12, 605-618. [Google Scholar] [CrossRef] 
[28] Wang, J., Yu, J., Chen, X., Zeng, Z., He, S., Liu, H., et al. (2025) Dual Electronic and Structural Engineering of Ni-Fe Alloys via Molten Salt Electrodeposition for Enhanced Oxygen Evolution Reaction. Advanced Functional Materials. [Google Scholar] [CrossRef] 
[29] Gao, W., Lin, J., Wang, K., Liu, Z., Qin, J., Xie, J., et al. (2018) Controllable Phosphorsulfurization of Uniform Binary Ni-Fe Nanocubes for Enhanced Water Oxidation. Materials Letters, 229, 248-251. [Google Scholar] [CrossRef] 
[30] Wang, Y., Yu, J., Wang, Y., Chen, Z., Dong, L., Cai, R., et al. (2020) In Situ Templating Synthesis of Mesoporous Ni-Fe Electrocatalyst for Oxygen Evolution Reaction. RSC Advances, 10, 23321-23330. [Google Scholar] [CrossRef] [PubMed]
[31] Rosa, M., Costa Bassetto, V., Girault, H.H., Lesch, A. and Esposito, V. (2019) Assembling Ni-Fe Layered Double Hydroxide 2D Thin Films for Oxygen Evolution Electrodes. ACS Applied Energy Materials, 3, 1017-1026. [Google Scholar] [CrossRef] 
[32] Zhou, F., Gan, M., Yan, D., Chen, X. and Peng, X. (2023) Hydrogen‐Rich Pyrolysis from Ni‐Fe Heterometallic Schiff Base Centrosymmetric Cluster Facilitates NiFe Alloy for Efficient OER Electrocatalysts. Small, 19, Article ID: 2208276. [Google Scholar] [CrossRef] [PubMed]

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