基于相图热力学数据库的Al-Si-Mg-Ce系列材料设计及可靠性研究
Design and Reliability Assessment of Al-Si-Mg-Ce Alloys Based on a CALPHAD Thermodynamic Database
DOI: 10.12677/ms.2025.1511218, PDF,    科研立项经费支持
作者: 冯恩浪*:辽宁知恩新材料科技有限公司,辽宁 沈阳;大连理工大学材料科学与工程学院,辽宁 大连;祝 哮, 王乐洋, 满瑞平:辽宁象屿铝业有限公司,辽宁 辽阳;张宇博:大连理工大学材料科学与工程学院,辽宁 大连;喻 亮:桂林理工大学材料科学与工程学院,广西 桂林;周 斌:中车戚墅堰机车车辆工艺研究所股份有限公司,江苏 常州;何建贤, 邓桂英, 黄 飞:广西南南铝加工有限公司,广西 南宁;毛一帆:广西平果百矿高新铝业有限公司,广西 百色;卢 照:桂林电子科技大学材料科学与工程学院,广西 桂林
关键词: CALPHAD计算相图Al-Si-Mg数据库可靠性 CALPHAD Computational Phase Diagram Al-Si-Mg Database Reliability
摘要: 本工作通过CALPHAD方法获得Al-Si-Mg-Ce相图热力学数据库。通过比较Al-7Si-0.6Mg-0.4Ce关键四元合金的Scheil凝固模拟和实验测定的相变温度与凝固微观组织,验证了所建立的热力学数据库的可靠性。结果表明,热力学计算和实验结果的高度吻合,证明了建立的Al-Si-Mg-Ce热力学数据库的可靠性,为Al-Si-Mg材料设计提供一种策略。
Abstract: In this work, a thermodynamic database for the Al-Si-Mg-Ce system was established via the CALPHAD approach. The reliability of the developed database was validated by comparing the Scheil solidification simulation of the key quaternary alloy Al-7Si-0.6Mg-0.4Ce with experimentally determined phase transformation temperatures and solidification microstructure. Results demonstrate a high consistency between thermodynamic calculations and experimental data, confirming the reliability of the constructed Al-Si-Mg-Ce thermodynamic database and providing a strategic pathway for the design of Al-Si-Mg-based materials.
文章引用:冯恩浪, 祝哮, 张宇博, 王乐洋, 满瑞平, 喻亮, 周斌, 何建贤, 邓桂英, 毛一帆, 黄飞, 卢照. 基于相图热力学数据库的Al-Si-Mg-Ce系列材料设计及可靠性研究[J]. 材料科学, 2025, 15(11): 2051-2060. https://doi.org/10.12677/ms.2025.1511218

参考文献

[1] Sanchez, J.M., Galarraga, H., Marquez, I. and de Cortazar, M.G. (2025) High-Throughput CALPHAD-Guided Design and Experimental Study on the Development of a Novel Multicomponent As-Cast Al-Si-Cu-Zn-Fe-Mn-Mg Based Alloy through the Direct Melting of Post-Consumer Scrap. Journal of Alloys and Compounds, 1015, Article ID: 178888. [Google Scholar] [CrossRef
[2] Akopyan, T.K., Belov, N.A., Lukyanchuk, A.A., Letyagin, N.V., Milovich, F.O. and Fortuna, A.S. (2022) Characterization of Structure and Hardness at Aging of the A319 Type Aluminum Alloy with Sn Trace Addition. Journal of Alloys and Compounds, 921, Article ID: 166109. [Google Scholar] [CrossRef
[3] Dinsdale, A.T. (1991) SGTE Data for Pure Elements. Calphad, 15, 317-425. [Google Scholar] [CrossRef
[4] Odinaev, K.O., Ganiev, I.N., Kinzybalo, V.V., et al. (1989) Phase Equilibria in the Al-Mg-Y and Al-Mg-Ce Systems at 673 k. Izvvyssich ucebnych zavedenij, Cvetnaja metallurgija, 2, 75-77.
[5] Sundman, B. and Ågren, J. (1981) A Regular Solution Model for Phases with Several Components and Sublattices, Suitable for Computer Applications. Journal of Physics and Chemistry of Solids, 42, 297-301. [Google Scholar] [CrossRef
[6] Gröbner, J., Kevorkov, D. and Schmid-Fetzer, R. (2002) Thermodynamic Modeling of Al-Ce-Mg Phase Equilibria Coupled with Key Experiments. Intermetallics, 10, 415-422. [Google Scholar] [CrossRef
[7] Sundman, B., Jansson, B. and Andersson, J. (1985) The Thermo-Calc Databank System. Calphad, 9, 153-190. [Google Scholar] [CrossRef
[8] Gröbner, J., Mirković, D. and Schmid-Fetzer, R. (2004) Thermodynamic Aspects of the Constitution, Grain Refining, and Solidification Enthalpies of Al-Ce-Si Alloys. Metallurgical and Materials Transactions A, 35, 3349-3362. [Google Scholar] [CrossRef
[9] Saccone, A., Macciò, D., Delfino, S., Hayes, F.H. and Ferro, R. (2001) Mg-Ce Alloys. Experimental Investigation by Smith Thermal Analysis. Journal of Thermal Analysis and Calorimetry, 66, 47-57. [Google Scholar] [CrossRef
[10] Voge, R. and Heumann, T. (1947) Determination of Ce-Mg and La-Mg Systems. Zeitschrift fur Metallkunde, 38, 1-8.
[11] Flandorfer, H. and Rogl, P. (1996) The Crystal Structure of Two Novel Compounds: CeAlSi2 and Ce3Al4Si6. Journal of Solid State Chemistry, 127, 308-314. [Google Scholar] [CrossRef
[12] Lu, Z. and Zhang, L. (2017) Thermal Stability and Crystal Structure of High-Temperature Compound Al13CeMg6. Intermetallics, 88, 73-76. [Google Scholar] [CrossRef