一种含钴磷钼金属氧簇化合物的合成、结构及其光催化活性研究
A Cobalt-Containing Phosphomolybdenum Metal-Oxygen Cluster Compound: Synthesis, Structure, and Photocatalytic Activity
DOI: 10.12677/ms.2025.1511219, PDF,    科研立项经费支持
作者: 彭 康, 游雅洁, 涂梅婷, 林兰馨, 郑涵逸, 黄晓辉*：宁德师范学院新能源与材料学院，福建 宁德
关键词: 水热合成；多酸；光催化活性；吸附性能；Hydrothermal Synthesis； Polyacid； Photocatalytic Activity； Adsorption Performance
摘要: 采用水热法合成出一种未见文献报道的化合物[(C4H9)4N]3[Co(H2O)2Co(C7H6N2)PMo12O40]。通过X-射线单晶衍射确定其是由一个[Co(H2O)2Co(C7H6N2)PMo12O40]簇离子，3个[(C4H9)4N]分子与配位水通过氢键形成连接形成的三维超分子结构。并对该化合物进行X-射线粉末衍射、红外、热重等一系列表征。对化合物的光催化活性与吸附性能进行研究，实验结果表明该化合物具有一定的光催化活性与吸附性能。
Abstract: A compound[(C4H9)4N]3[Co(H2O)2Co(C7H6N2)PMo12O40], which has not been reported in the literature, was synthesized by hydrothermal method. It was determined by X-ray single crystal diffraction that it is a three-dimensional supramolecular structure formed by a [Co(H2O)2Co(C7H6N2)PMo12O40] cluster ion, three [(C4H9)4N] molecules and coordination water through hydrogen bonding. A series of characterizations of the compound were carried out by X-ray powder diffraction, infrared, thermogravimetry and so on. The photocatalytic activity and adsorption properties of the compound were studied, and the experimental results showed that the compound had certain photocatalytic activity and adsorption properties.
文章引用：彭康, 游雅洁, 涂梅婷, 林兰馨, 郑涵逸, 黄晓辉. 一种含钴磷钼金属氧簇化合物的合成、结构及其光催化活性研究[J]. 材料科学, 2025, 15(11): 2061-2070. https://doi.org/10.12677/ms.2025.1511219

参考文献

[1] 王恩波. 多酸化学概论[M]. 长春: 东北师范大学出版社, 2009.
[2] Aleksandar, B., Manuel, A. and Annette, R. (2018) Polyoxometalates as Potential Next-Generation Metallodrugs in the Combat against Cancer. Angewandte Chemie International Edition, 57, 2-22.
[3] Croce, M., Conti, S., Maake, C. and Patzke, G.R. (2018) Nanocomposites of Polyoxometalates and Chitosan-Based Polymers as Tuneable Anticancer Agents. European Journal of Inorganic Chemistry, 2019, 348-356. [Google Scholar] [CrossRef] 
[4] Wang, S. and Yang, G. (2015) Recent Advances in Polyoxometalate-Catalyzed Reactions. Chemical Reviews, 115, 4893-4962. [Google Scholar] [CrossRef] [PubMed]
[5] Patel, A. and Sadasivan, R. (2021) Modified Mn Substituted Poms: Synthetic Strategies, Structural Diversity to Applications. Progress in Materials Science, 118, Article 100759. [Google Scholar] [CrossRef] 
[6] Wang, C., Su, T., Zang, H. and Su, Z. (2023) Rational Design and Progress of Molybdenum-Oxo Clusters. Materials Chemistry Frontiers, 7, 1912-1942. [Google Scholar] [CrossRef] 

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