多环芳烃衍生物检测分析方法研究进展
Research Progress on Detection and Analysis Methods of Polycyclic Aromatic Hydrocarbons Derivatives
DOI: 10.12677/ms.2025.1511225, PDF,   
作者: 张靖松, 周文清, 程鑫林, 胡微勇, 蒋若曼, 潘锁柱*：西华大学汽车与交通学院，四川 成都；汽车测控与安全四川省重点实验室，四川 成都
关键词: PAHs衍生物；样品采集；样品预处理；检测分析方法 ；Pahs Derivatives； Sample Collection； Sample Pre-Treatment； Detection and Analysis Methods
摘要: 多环芳烃(PAHs)衍生物是新兴的环境污染物，分布范围广，浓度低，检测难度大。鉴于此，基于国内外研究成果，针对PAHs衍生物的样品采集、样品预处理和样品分析进行了梳理和总结。样品采集包括气相样品采集、固相样品采集和液相样品采集。样品预处理有索氏萃取法、超声波萃取法和加压溶剂萃取法。样品分析方法主要有气相色谱质谱联用法(GC-MS)、气相色谱串联质谱法(GC-MS/MS)、二维气相色谱串联质谱法(GC × GC-MS/MS)和液相色谱串联质谱法(LC-MS/MS)。GC-MS、GC-MS/MS和GC × GC-MS/MS主要用于非极性或弱极性的小分子PAHs衍生物，LC-MS/MS主要用于高极性的大分子PAHs衍生物。本文旨在为提高PAHs衍生物检测的便捷性、精确性和可靠性提供依据，促进PAHs衍生物的系统研究以及汽车、移动源等排放法规的制定。
Abstract: Polycyclic aromatic hydrocarbons (PAHs) derivatives are emerging environmental pollutants characterized by a wide distribution, low concentration, and significant difficulty in detection. Therefore, this paper sorted out and summarized the sample collection, sample pre-treatment and sample analysis of PAH derivatives based on the research findings over the worldwide. Sample collection includes gas phase sample collection, solid phase sample collection, and liquid phase sample collection. Sample pre-treatment include soxhlet extraction method, ultrasonic extraction method, and pressurized solvent extraction method. The main methods for sample analysis include gas chromatography-mass spectrometry (GC-MS), gas chromatography tandem mass spectrometry (GC-MS/MS), two-dimensional gas chromatography tandem mass spectrometry (GC × GC-MS/MS), and liquid chromatography tandem mass spectrometry (LC-MS/MS). GC-MS, GC-MS/MS, and GC × GC-MS/MS are mainly used for non-polar or weakly polar small-molecule PAHs derivatives, while LC-MS/MS is mainly used for highly polar large-molecule PAHs derivatives. This paper aims to provide a basis for improving the convenience, accuracy, and reliability of PAHs derivatives detection, thereby facilitating systematic research on PAHs derivatives and formulating emission regulations for automobiles, mobile sources and other sources.
文章引用：张靖松, 周文清, 程鑫林, 胡微勇, 蒋若曼, 潘锁柱. 多环芳烃衍生物检测分析方法研究进展[J]. 材料科学, 2025, 15(11): 2120-2129. https://doi.org/10.12677/ms.2025.1511225

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