微胶囊自修复混凝土修复效率对比分析研究综述
Research Review on Comparative Analysis of Microencapsulated Self-Repairing Concrete Repair Efficiency
摘要: 微胶囊自修复技术是一种能够提升混凝土结构耐久性和安全性的前沿方法,从微胶囊囊芯和囊壳的构建材料、制备工艺以及修复机理这些方面入手,着重对比分析了影响它修复效率的关键因素,这些因素包含微胶囊参数、修复触发机制,以及修复效果评估方法,修复效率可以从强度恢复率、裂缝闭合度、渗透性恢复等多个不同的维度来衡量,而且它受到微胶囊与混凝土基体相容性以及环境条件的影响非常显著。本文在综述现有研究结论的基础上,增加批判性分析视角,探讨不同研究测试方法差异对结果可比性的影响,并基于现有研究提炼指导实践的设计原则与技术路线图,为高性能自修复混凝土的设计与应用提供更具价值的理论参考。
Abstract: Microcapsule self-repairing technology is a cutting-edge method to enhance the durability and safety of concrete structures. Starting from the construction materials of microcapsule core and capsule shell, the preparation process, and the repair mechanism, we focus on comparing and analysing the key factors affecting the repair efficiency of the microcapsule, which include the parameters of the microcapsule, the repair triggering mechanism, and the method of evaluating the repair effect, which can be measured from the different dimensions, such as strength recovery, crack closure, and permeability recovery. The repair efficiency can be measured from the strength recovery rate, crack closure, permeability recovery and other different dimensions, and it is significantly affected by the compatibility of microcapsules with the concrete matrix and environmental conditions. This paper summarises the current challenges faced by this technology and provides an outlook on future research directions, with the aim of providing theoretical references for the design and application of high-performance self-repairing concrete. Building upon a review of existing research findings, this paper introduces a critical analytical perspective to examine how variations in testing methodologies affect the comparability of results. Drawing from current studies, it distils design principles and technical roadmaps to guide practical implementation, thereby providing more valuable theoretical reference for the design and application of high-performance self-healing concrete.
文章引用:万奕, 孙洪军. 微胶囊自修复混凝土修复效率对比分析研究综述[J]. 土木工程, 2025, 14(12): 2869-2877. https://doi.org/10.12677/hjce.2025.1412308

参考文献

[1] Liu, B., Wu, M., Du, W., Jiang, L., Li, H., Wang, L., et al. (2023) The Application of Self-Healing Microcapsule Technology in the Field of Cement-Based Materials: A Review and Prospect. Polymers, 15, Article No. 2718. [Google Scholar] [CrossRef] [PubMed]
[2] 黄佳涛, 廖蔚彬, 吴沛宗, 等. 微胶囊技术在自愈合混凝土中的研究进展[J]. 混凝土, 2024(12): 229-235.
[3] Jiang, L., Wu, M., Du, F., Chen, D., Xiao, L., Chen, W., et al. (2024) State-of-the-Art Review of Microcapsule Self-Repairing Concrete: Principles, Applications, Test Methods, Prospects. Polymers, 16, Article No. 3165. [Google Scholar] [CrossRef] [PubMed]
[4] 房国豪, 陈锦妹, 王琰帅, 等. 微胶囊自修复混凝土研究进展[J]. 硅酸盐学报, 2023, 51(9): 2423-2432.
[5] Lee, Y.B., Suslick, B.A., de Jong, D., Wilson, G.O., Moore, J.S., Sottos, N.R., et al. (2023) A Self‐Healing System for Polydicyclopentadiene Thermosets. Advanced Materials, 36, Article ID: 2309662. [Google Scholar] [CrossRef] [PubMed]
[6] 张立卿, 边明强, 王云洋, 等. 自修复混凝土修复性能评估中的若干关键技术与方法研究综述[J]. 材料导报, 2024, 38(9): 78-100.
[7] Li, Z., Du, G., Yang, S., Lu, X., Zheng, F., Hao, B., et al. (2025) Self-Healing Imidazole-Cured Epoxy Using Microencapsulated Epoxy-Amine Chemistry. Polymers, 17, Article No. 2391. [Google Scholar] [CrossRef
[8] Puhurcuoğlu, N. and Arman, Y. (2024) Parameter Estimation of Epoxy Resin Cure Kinetics by Dynamics DSC Data. Polymers for Advanced Technologies, 35, e6498. [Google Scholar] [CrossRef
[9] Liu, J., Cui, X., Qin, J., Shi, M., Wang, D., Yang, L., et al. (2024) Ultra-High Cross-Linked Active Ester-Cured Epoxy Resins: Side Group Cross-Linking for Performance Enhancement. Polymer, 301, Article ID: 127063. [Google Scholar] [CrossRef
[10] Dong, S., Li, X., Li, Z., Zhu, Y. and Li, H. (2025) Robust Poly(Urea-Formaldehyde)/Sodium Alginate Microcapsules for Achieving Efficient Self-Healing in Concrete. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 717, Article ID: 136760. [Google Scholar] [CrossRef
[11] 吕乐阳, 张翔宇, 董必钦, 等. 自修复混凝土触发机制设计方法综述[J]. 材料导报, 2024, 38(20): 149-160.
[12] Song, Z., Zhang, S., Wang, J., Huang, Z., Jiang, L., Guo, M., et al. (2025) Preparation and Self-Healing Properties of Polyurea-MMT/HDI Microcapsules for Cement-Based Materials. Journal of Building Engineering, 107, Article ID: 112791. [Google Scholar] [CrossRef
[13] Han, Y., Dai, W., Ju, Y., Wang, D., Liu, M., Zhou, L., et al. (2025) The Synthesis of Hexamethylene Diisocyanate Microcapsules and Mechanisms of Self-Healing Geopolymer through an Isocyanate-Hydroxy System. Case Studies in Construction Materials, 22, e04581. [Google Scholar] [CrossRef
[14] Kothari, J. and Iroh, J.O. (2023) Self-Healing Poly(Urea Formaldehyde) Microcapsules: Synthesis and Characterization. Polymers, 15, Article No. 1668. [Google Scholar] [CrossRef] [PubMed]
[15] Du, W., Yu, J., Gu, Y., Li, Y., Han, X. and Liu, Q. (2019) Preparation and Application of Microcapsules Containing Toluene-Di-Isocyanate for Self-Healing of Concrete. Construction and Building Materials, 202, 762-769. [Google Scholar] [CrossRef
[16] De Nardi, C., Gardner, D., Cazzador, G., Cristofori, D., Ronchin, L., Vavasori, A., et al. (2021) Experimental Investigation of a Novel Formulation of a Cyanoacrylate-Based Adhesive for Self-Healing Concrete Technologies. Frontiers in Built Environment, 7, Article ID: 660562. [Google Scholar] [CrossRef
[17] Mao, W., Litina, C. and Al-Tabbaa, A. (2020) Development and Application of Novel Sodium Silicate Microcapsule-Based Self-Healing Oil Well Cement. Materials, 13, Article No. 456. [Google Scholar] [CrossRef] [PubMed]
[18] Hou, F., Guo, Z., Hui, Y. and Zhao, C. (2025) Biomimetic Fabrication of Silica Microcapsules Using Bifunctional Peptides. Advanced Materials Interfaces, 12, e00221. [Google Scholar] [CrossRef
[19] Khorasani, S.N., Ataei, S. and Neisiany, R.E. (2017) Microencapsulation of a Coconut Oil-Based Alkyd Resin into Poly(Melamine-Urea-Formaldehyde) as Shell for Self-Healing Purposes. Progress in Organic Coatings, 111, 99-106. [Google Scholar] [CrossRef
[20] Li, J., Guan, X. and Zhang, C. (2023) Inorganic Capsule Based on Expansive Mineral for Self-Healing Concrete. Cement and Concrete Composites, 144, Article ID: 105305. [Google Scholar] [CrossRef
[21] 赵尚传, 李小鹏, 王少鹏. 混凝土自修复微胶囊壁材的研究现状与进展[J]. 材料导报, 2020, 34(S2): 1201-1205.
[22] Esma, B., Erkut, Y., Mehmet, Y., et al. (2023) Effect of Using Capsules with Waste Mineral Oil on Self-Healing of Long-Term Aged Hot-Mix Asphalt. Journal of Materials in Civil Engineering, 35, 103648. [Google Scholar] [CrossRef
[23] 周小燕, 杨淘, 代薇, 等. 基于DIC技术的修复后混凝土裂缝扩展特性试验研究[J]. 水电能源科学, 2025, 43(7): 119-122+68.
[24] Pandey, A., Sharma, A.K., Shukla, D.K. and Pandey, K.N. (2023) Effect of Self-Healing by Dicyclopentadiene Microcapsules on Tensile and Fatigue Properties of Epoxy Composites. Materials, 16, Article No. 5191. [Google Scholar] [CrossRef] [PubMed]
[25] Li, Y., Yu, J., Cao, Z., He, P., Liu, Q., Han, X., et al. (2021) Preparation and Application of Novel Microcapsules Ruptured by Microwave for Self-Healing Concrete. Construction and Building Materials, 304, Article ID: 124616. [Google Scholar] [CrossRef
[26] Urdl, K., Weiss, S., Christöfl, P., Kandelbauer, A., Müller, U. and Kern, W. (2020) Diels-Alder Modified Self-Healing Melamine Resin. European Polymer Journal, 127, Article ID: 109601. [Google Scholar] [CrossRef
[27] Han, K., Ju, J.W., Chen, X., Lv, L., Zhou, S., Wei, G., et al. (2024) A 3D Micromechanical Model to Predict the Complete Stress-Strain Relation of Microencapsulated Self-Healing Concrete. International Journal of Damage Mechanics, 34, 3-25. [Google Scholar] [CrossRef
[28] Rengaraju, S., Arena, N., Kanavaris, F., Jędrzejewska, A. and Al-Tabbaa, A. (2025) Environmental Life Cycle Assessment of Self-Healing Concrete with Microcapsules and Impregnated Lightweight Aggregates. Journal of Building Engineering, 111, Article ID: 113105. [Google Scholar] [CrossRef
[29] Kim, J.R. and Netravali, A.N. (2017) Self-Healing Starch-Based “Green” Thermoset Resin. Polymer, 117, 150-159. [Google Scholar] [CrossRef
[30] Jiang, W., Zhou, G., Wang, C., Xue, Y. and Niu, C. (2021) Synthesis and Self-Healing Properties of Composite Microcapsule Based on Sodium Alginate/Melamine-Phenol-Formaldehyde Resin. Construction and Building Materials, 271, Article ID: 121541. [Google Scholar] [CrossRef
[31] Lv, J., Niu, S., Zhang, W. and Sun, Y. (2025) Study on Self-Healing Effect of Concrete Based on Epoxy Resin Adhesive. Materials, 18, Article No. 2679. [Google Scholar] [CrossRef] [PubMed]
[32] 陈自敏, 冉志红, 张艳, 等. 混凝土裂缝修复用改性环氧树脂的多目标优化[J]. 材料导报, 2025, 39(10): 252-260.