金属有机框架膜在H2/CO2分离上的研究进展
Research Progress on Metal-Organic Framework Membranes for H₂/CO₂ Separation
DOI: 10.12677/aac.2026.161002, PDF,   
作者: 杨茂春, 周 丹, 李 丹, 冯 悦：浙江师范大学含氟新材料研究所，先进催化材料教育部重点实验室，浙江 金华
关键词: H2/CO2分离；膜分离；金属有机框架膜；H₂/CO₂ Separation； Membrane Separation； Metal-Organic Framework Membranes
摘要: H2/CO2分离是生产清洁能源和减少温室气体排放、实现可持续发展和应对气候变化挑战的关键步骤。传统分离技术能耗高，而膜分离技术因其节能、操作简单、规模灵活等优势备受关注。金属–有机框架(MOF)膜，凭借其高度有序的孔道结构、可调的孔径与化学环境，为突破传统聚合物膜面临的“渗透性–选择性”权衡上限提供了革命性平台。综述了不同类型MOFs膜(多晶连续膜、混合基质膜(MMMs)及二维MOF (2D-MOF)膜，介绍了它们的特点和优势，并阐明了最佳使用条件。总结了膜设计的关键问题，如多相设计、微结构控制、分离机理。最后提出了MOF膜分离H2、CO2面临的主要挑战和未来的研究前景。
Abstract: H₂/CO₂ separation is a critical step in producing clean energy and reducing greenhouse gas emissions, which is essential for achieving sustainable development and addressing climate change challenges. Conventional separation technologies are often energy-intensive, whereas membrane separation technology has attracted significant attention due to its energy efficiency, operational simplicity, and scalability. Metal-organic framework (MOF) membranes, with their highly ordered pore structures, tunable pore sizes, and adjustable chemical environments, offer a revolutionary platform to overcome the upper bound of the “permeability-selectivity” trade-off faced by traditional polymer membranes. This review summarizes different types of MOF membranes, including polycrystalline continuous membranes, mixed-matrix membranes (MMMs), and two-dimensional MOF (2D-MOF) membranes, highlighting their characteristics and advantages while clarifying their optimal operating conditions. Key issues in membrane design are discussed, such as multi-phase design, microstructure control, and separation mechanisms. Finally, the main challenges and future research prospects for MOF membranes in H₂ and CO₂ separation are outlined.
文章引用：杨茂春, 周丹, 李丹, 冯悦. 金属有机框架膜在H2/CO2分离上的研究进展[J]. 分析化学进展, 2026, 16(1): 9-17. https://doi.org/10.12677/aac.2026.161002

参考文献

[1] Hu, L., Pal, S., Nguyen, H., Bui, V. and Lin, H. (2020) Molecularly Engineering Polymeric Membranes for H2/CO2 Separation at 100-300 °c. Journal of Polymer Science, 58, 2467-2481. [Google Scholar] [CrossRef] 
[2] Cardoso, S.P., Azenha, I.S., Lin, Z., Portugal, I., Rodrigues, A.E. and Silva, C.M. (2017) Inorganic Membranes for Hydrogen Separation. Separation & Purification Reviews, 47, 229-266. [Google Scholar] [CrossRef] 
[3] Ma, J., Li, L., Wang, H., Du, Y., Ma, J., Zhang, X., et al. (2022) Carbon Capture and Storage: History and the Road Ahead. Engineering, 14, 33-43. [Google Scholar] [CrossRef] 
[4] Chuah, C., Lee, J. and Bae, T. (2020) Graphene-Based Membranes for H2 Separation: Recent Progress and Future Perspective. Membranes, 10, Article 336. [Google Scholar] [CrossRef] [PubMed]
[5] Xu, R., He, L., Li, L., Hou, M., Wang, Y., Zhang, B., et al. (2020) Ultraselective Carbon Molecular Sieve Membrane for Hydrogen Purification. Journal of Energy Chemistry, 50, 16-24. [Google Scholar] [CrossRef] 
[6] Robeson, L.M. (2008) The Upper Bound Revisited. Journal of Membrane Science, 320, 390-400. [Google Scholar] [CrossRef] 
[7] Furukawa, H., Cordova, K.E., O’Keeffe, M. and Yaghi, O.M. (2013) The Chemistry and Applications of Metal-Organic Frameworks. Science, 341, Article 1230444. [Google Scholar] [CrossRef] [PubMed]
[8] Sun, S., Li, S., Wang, S. and Chen, Y. (2024) Design and Development of Highly Selective and Permeable Membranes for H2/CO2 Separation—A Review. Chemical Engineering Journal, 494, Article 152972. [Google Scholar] [CrossRef] 
[9] Lombardo, S.J. and Bell, A.T. (1991) A Review of Theoretical Models of Adsorption, Diffusion, Desorption, and Reaction of Gases on Metal Surfaces. Surface Science Reports, 13, 3-72. [Google Scholar] [CrossRef] 
[10] Yang, M., He, F., Zhou, C., Dong, F., Yang, G., Zhou, W., et al. (2021) New Perovskite Membrane with Improved Sintering and Self-Reconstructed Surface for Efficient Hydrogen Permeation. Journal of Membrane Science, 620, Article 118980. [Google Scholar] [CrossRef] 
[11] Wijmans, J.G. and Baker, R.W. (1995) The Solution-Diffusion Model: A Review. Journal of Membrane Science, 107, 1-21. [Google Scholar] [CrossRef] 
[12] Park, G.S. (1986) Transport Principles—Solution, Diffusion and Permeation in Polymer Membranes. In: Bungay, P.M., Lonsdale, H.K. and de Pinho, M.N., Eds., Synthetic Membranes: Science, Engineering and Applications, Springer Netherlands, 57-107. [Google Scholar] [CrossRef] 
[13] Bayati, B., Ghorbani, A., Ghasemzadeh, K., Iulianelli, A. and Basile, A. (2019) Study on the Separation of H2 from CO2 Using a ZIF-8 Membrane by Molecular Simulation and Maxwell-Stefan Model. Molecules, 24, Article 4350. [Google Scholar] [CrossRef] [PubMed]
[14] Yang, K., Hu, S., Ban, Y., Zhou, Y., Cao, N., Zhao, M., et al. (2021) ZIF-L Membrane with a Membrane-Interlocked-Support Composite Architecture for H2/CO2 Separation. Science Bulletin, 66, 1869-1876. [Google Scholar] [CrossRef] [PubMed]
[15] Abdul Hamid, M.R., Qian, Y., Wei, R., Li, Z., Pan, Y., Lai, Z., et al. (2021) Polycrystalline Metal-Organic Framework (MOF) Membranes for Molecular Separations: Engineering Prospects and Challenges. Journal of Membrane Science, 640, Article 119802. [Google Scholar] [CrossRef] 
[16] Liu, H., Cong, S., Yan, X., Wang, X., Gao, A., Wang, Z., et al. (2023) Honeycomb-Like Hofmann-Type Metal-Organic Framework Membranes for C2H2/CO2 and H2/CO2 Separation. Journal of Membrane Science, 669, Article 121282. [Google Scholar] [CrossRef] 
[17] Ji, T., Sun, Y., Liu, Y., Li, M., Wang, F., Liu, L., et al. (2020) Facile in Situ Hydrothermal Synthesis of Layered Zirconium Phenylphosphonate Molecular Sieve Membranes with Optimized Microstructure and Superb H2/CO2 Selectivity. ACS Applied Materials & Interfaces, 12, 15320-15327. [Google Scholar] [CrossRef] [PubMed]
[18] Sun, Y., Yan, J., Gao, Y., Ji, T., Chen, S., Wang, C., et al. (2023) Fabrication of Highly Oriented Ultrathin Zirconium Metal‐Organic Framework Membrane from Nanosheets Towards Unprecedented Gas Separation. Angewandte Chemie International Edition, 62, e202216697. [Google Scholar] [CrossRef] [PubMed]
[19] Dechnik, J., Gascon, J., Doonan, C.J., Janiak, C. and Sumby, C.J. (2017) Mixed‐Matrix Membranes. Angewandte Chemie International Edition, 56, 9292-9310. [Google Scholar] [CrossRef] [PubMed]
[20] Kamble, A.R., Patel, C.M. and Murthy, Z.V.P. (2021) A Review on the Recent Advances in Mixed Matrix Membranes for Gas Separation Processes. Renewable and Sustainable Energy Reviews, 145, Article 111062. [Google Scholar] [CrossRef] 
[21] Hu, L., Bui, V.T., Pal, S., Guo, W., Subramanian, A., Kisslinger, K., et al. (2022) In Situ Growth of Crystalline and Polymer‐Incorporated Amorphous ZIFs in Polybenzimidazole Achieving Hierarchical Nanostructures for Carbon Capture. Small, 18, Article 2201982. [Google Scholar] [CrossRef] [PubMed]
[22] Wu, X., Tian, Z., Wang, S., Peng, D., Yang, L., Wu, Y., et al. (2017) Mixed Matrix Membranes Comprising Polymers of Intrinsic Microporosity and Covalent Organic Framework for Gas Separation. Journal of Membrane Science, 528, 273-283. [Google Scholar] [CrossRef] 
[23] Zhao, M., Huang, Y., Peng, Y., Huang, Z., Ma, Q. and Zhang, H. (2018) Two-Dimensional Metal-Organic Framework Nanosheets: Synthesis and Applications. Chemical Society Reviews, 47, 6267-6295. [Google Scholar] [CrossRef] [PubMed]
[24] Peng, Y., Li, Y., Ban, Y., Jin, H., Jiao, W., Liu, X., et al. (2014) Metal-Organic Framework Nanosheets as Building Blocks for Molecular Sieving Membranes. Science, 346, 1356-1359. [Google Scholar] [CrossRef] [PubMed]
[25] Yang, F., Wu, M., Wang, Y., Ashtiani, S. and Jiang, H. (2018) A Go-Induced Assembly Strategy to Repair MOF Nanosheet-Based Membrane for Efficient H2/CO2 Separation. ACS Applied Materials & Interfaces, 11, 990-997. [Google Scholar] [CrossRef] [PubMed]
[26] Song, H., Peng, Y., Wang, C., Shu, L., Zhu, C., Wang, Y., et al. (2023) Structure Regulation of MOF Nanosheet Membrane for Accurate H2/CO2 Separation. Angewandte Chemie International Edition, 62, e202218472. [Google Scholar] [CrossRef] [PubMed]

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