离子液体1-丁基-3-羧甲基苯并三唑三氟乙酸盐催化三组分缩合反应合成氨基萘酚化合物
Ionic Liquid 1-Butyl-3-Carboxymethyl Benzotriazole Trifluoroacetate Catalyzed Three Component Condensation Reaction for the Synthesis of Aminonaphthols
DOI: 10.12677/JOCR.2017.52009, PDF,    国家自然科学基金支持
作者: 郭 磊, 麻 荣, 张增鹏, 刘晨江：石油天然气精细化工教育部&自治区重点实验室，新疆大学理化测试中心，新疆 乌鲁木齐
关键词: 离子液体；氨基萘酚；催化；合成；无溶剂；Ionic Liquid； Aminonaphthols； Catalysis； Synthesis； Solvent-Free
摘要: 本文报道了一种离子液体1-丁基-3-羧甲基苯并三唑三氟乙酸盐催化β-萘酚、芳香醛和胺在无溶剂条件下发生三组分缩合反应绿色、高效合成氨基萘酚化合物的方法。离子液体催化剂至少可以循环使用5次，并且活性没有明显降低。
Abstract: A green and highly efficient approach for the synthesis of aminonaphthols via ionic liquid 1-butyl-3-carboxymethyl benzotriazole trifluoroacetate catalyzed three component condensation recation of β-naphthols, aromatic aldehydes and amines under solvent-free conditions has been reported. The catalyst ionic liquid can be easily recycled and reused for at least five cycles without obvious loss of catalytic activity.
文章引用：郭磊, 麻荣, 张增鹏, 刘晨江. 离子液体1-丁基-3-羧甲基苯并三唑三氟乙酸盐催化三组分缩合反应合成氨基萘酚化合物[J]. 有机化学研究, 2017, 5(2): 71-77. https://doi.org/10.12677/JOCR.2017.52009

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