富集B-10单质的制备
Preparation of Enriched Elemental B-10
摘要: 硼具有很强的中子吸收能力,这种能力来自于10B较大的中子吸收截面。富集B-10在辐射防护、燃料元件制造、中子探测等领域应用广泛,具有较大的研究价值。受限于硼同位素分离工艺,生产富集B-10同位素产品需要以10BF3 为起始原料。本文主要结合天然丰度元素硼的制备方法,提出了制备富集B-10单质的工艺路线,并对制备富集10B单质硼的各种方法的优势和不足进行了分析和说明。
Abstract: Boron has a strong neutron absorption capacity as 10B has a larger neutron absorption cross-section. Enriched B-10 is widely used in radiation protection, fuel element manufacturing, neutron detection and other fields, which ensures it with a great research value. Due to the bo-ron isotope separation process, the production of enriched B-10 isotope products requires the use of 10BF3 as a starting material. In this paper, we have compared the preparation method of natural abundance elemental boron, proposed several possible processes of preparing enriched elemental B-10, and analyzed the advantages and disadvantages of the various methods.
文章引用:胡小飞, 曾静, 肖楠林, 胡石林. 富集B-10单质的制备[J]. 核科学与技术, 2018, 6(2): 35-42. https://doi.org/10.12677/NST.2018.62005

参考文献

[1] 郑学家. 核工业用硼化物[M]. 北京: 化学工业出版社, 2015: 116.
[2] Chadwick, M.B., Herman, M., Obložinský, P., et al. (2011) Nuclear Data for Science and Technology: Cross Sections, Covariances, Fission Product Yields and Decay Data. Nuclear Data Sheets, 112, 2887-2996. [Google Scholar] [CrossRef
[3] Wang, L. (2000) The Position of Boron Carbide in Neutron Absorbing Materials and Its Properties Relation to Nuclear Applications. Materials Science & Engineering of Powder Metallargy, 5, 113-120.
[4] Arnaldi, R., Chiavassa, E., Colla, A., et al. (2006) Thermal Neutron Detection with Resistive Plate Chambers via the 10B(n, α)7 Li Reaction. Nuclear Physics B—Proceedings Supplements, 158, 177-181. [Google Scholar] [CrossRef
[5] Zheng, H., Ramalingam, B., Mukherjee, S., et al. (2016) Neutron Detection with Integrated sub-2 nm Pt Nanoparticles and 10B Enriched Dielectrics—A Direct Conversion Device. Sensing and Bio-Sensing Research, 9, 1-6. [Google Scholar] [CrossRef
[6] 厉井钢, 卢皓亮, 张洪, 等. 硼化锆在CPR1000核电厂1/4换料燃料管理中的应用研究[J]. 核动力工程, 2012, 33(5): 1-5.
[7] 罗全勇, 朱瑞森. 硼中子俘获治疗[J]. 同位素, 2004, 17(3): 174-177.
[8] Lintereur, A.T., Ely, J.H., Kouzes, R.T., et al. (2012) Boron-10 Lined Proportional Counter Model Validation. Nuclear Science Symposium and Medical Imaging Conference, Springfield, June 2012, 4290-4295.
[9] Li, J.-G., Lu, H.-L., Zhang, H., et al. (2012) Study on Application of Zirconium Diboride(ZrB2) in CPR1000 Quarter-Core Fuel Management. Nuclear Power Engineering, 33, 1-5.
[10] 于景阳, 韩莉果, 张卫江, 等. 化学交换反应法分离硼同位素的数学模型[J]. 同位素, 2005, 18(4): 216-219.
[11] Huang, Y., Cheng, S., Xu, J., et al. (2011) Research on Chemical Exchange Process of Boron Isotope Separation. Procedia Engineering, 18, 151-156. [Google Scholar] [CrossRef
[12] Itoh, S., Aida, M., Okamoto, M., et al. (2008) Boron Isotope Separation by Ion Exchange Chromatography Using Weakly Basic Anion Exchange Resin. Isotopenpraxis Isotopes in Environmental & Health Studies, 21, 204-208.
[13] Zhou, F., Zhang, J., Bai, P., et al. (2016) Theoretical Calculation of Boron Isotopic Separation Factors in Ion-Exchange Chromatography. Journal of Chemical & Engi-neering Data, 62, 525-531.
[14] Lyakhov, K. and Lee, H.J. (2015) New Experimental Setup for Boron Isotopes Separation by the Laser Assisted Retardation of Condensation Method. Journal of Nanoscience & Nanotechnology, 262, 579-587. [Google Scholar] [CrossRef] [PubMed]
[15] Lyakhov, K.A., Lee, H.J. and Pechen, A.N. (2017) Some Issues of Industrial Scale Boron Isotopes Separation by the Laser Assisted Retarded Condensation (SILARC) Method. Separation & Purification Technology, 176, 402-411. [Google Scholar] [CrossRef
[16] 李建平. 硼同位素分离工艺与生产技术[J]. 同位素, 2014, 27(2): 87-92.
[17] Dou, Z.H. and Zhang T.A. (2004) Preparation of Boron Powder by Self-Propagating High Temperature Synthesis Metallurgy. Chinese Journal of Nonferrous Metals, 14, 2137-2143.
[18] 喇培清, 卢学峰, 申达, 等. 铝热还原法制备硼粉[J]. 粉末冶金材料科学与工程, 2012, 17(6): 748-753.
[19] Peng, C., Chen, S., Wu, Y., et al. (2010) Preparation of Boron Powder by Molten Salt Electrolysis. Chinese Journal of Rare Metals, 34, 264-270.
[20] 张慧敏. 熔融电解法制备硼-10粉[J]. 辽宁化工, 1993(6): 33-36.
[21] White, M.A., Cerqueira, A.B., Whitman, C.A., et al. (2015) Determination of Phase Stability of Elemental Boron. Angewandte Chemie, 54, 3626-3629. [Google Scholar] [CrossRef] [PubMed]
[22] Zhang, L., Zhang, W. and Xu, J. (2015) Preparation of Boric-10 Acid Applied in Nuclear industry. Transactions of Tianjin University, 21, 172-177. [Google Scholar] [CrossRef
[23] Zhang, W., Liu, T. and Xu, J. (2016) Preparation and Characterization of 10B Boric Acid with High Purity for Nuclear Industry. Springerplus, 5, 1202. [Google Scholar] [CrossRef] [PubMed]
[24] 黄菊林. 金属镁热还原法制备非晶硼粉的研究[J]. 矿冶, 1996(3).
[25] 伍继君, 杨斌, 马文会, 等. 超细高能燃料无定形硼粉的自蔓延制备与表征[J]. 功能材料, 2007, 38(12): 2073-2076.
[26] Dou, Z.H., Zhang, T.A., Shi, G.Y., et al. (2014) Preparation and Characterization of Amorphous Boron Powder with High Activity. Transactions of Nonferrous Metals Society of China, 24, 1446-1451. [Google Scholar] [CrossRef
[27] 彭超. 自蔓延冶金法制备无定形硼粉中夹杂物分析及去除机制[D]: [硕士学位论文]. 沈阳: 东北大学, 2014.
[28] Neelameggham, N.R. (2012) Elemental Boron and Magnesium Boride Synthesis. Journal for Manufacturing Science & Production, 12, 155-160. [Google Scholar] [CrossRef
[29] Tilekar, K.V., Gajbhiye, V.P., Prasanth, H., et al. (2005) Preparation of High Purity Amorphous Boron Powder. Defence Science Journal, 55, 471-475. [Google Scholar] [CrossRef
[30] 彭程, 陈松, 吴延科, 等. 熔盐电解法制备硼粉的研究[J]. 稀有金属, 2010, 34(2): 000264.
[31] Mehra, R. (2013) High Pressure Synthesis and Investigation of Single Crystals of Metastable Boron Phases. High Pressure Research, 33, 673-683. [Google Scholar] [CrossRef
[32] 彭程, 陈松, 王力军, 等. 一种熔盐电解制备硼粉的方法及电解装置[P]. 中国专利, 2012.
[33] Copper, H.S. (1951) Electrolytic Method of Making Boron. US Patent No. 2572248.
[34] Alvin Uchiyama, A., et al. () (1960) Electrorefining of Elemental Boron. WO Patent No. 2940911.
[35] Copper, H.S. (1959) Production of Boron by Fused Salt Bath Electrolysis. US Patent No. 2918417.
[36] 徐华毕, 沈辉, 梁宗存. 太阳能级多晶硅生产与发展概况[J]. 材料导报, 2008, 22(9): 86-90.
[37] Tsai, C.C. (1979) Characterization of Amorphous Semiconducting Silicon-Boron Alloys Prepared by Plasma Decomposition. Physical Review B, 19, 2041-2055. [Google Scholar] [CrossRef
[38] Song, Z.F., Ye, S.Z., Chen, Z.Y., et al. (2011) Study on Boron-Film Thermal Neutron Converter Prepared by Pulsed Laser Deposition. Applied Radiation & Isotopes Including Data Instrumentation & Methods for Use in Agriculture Industry & Medicine, 69, 443-447. [Google Scholar] [CrossRef] [PubMed]
[39] Stern, D.R. and Lynds, L. (1958) High Purity Crystalline Boron. Journal of the Electrochemical Society, 105, 676-682. [Google Scholar] [CrossRef
[40] White, M.A., Cerqueira, A.B., Whitman, C.A., et al. (2015) Determination of Phase Stability of Elemental Boron. Angewandte Chemie International Edition, 127, 3697-3700. [Google Scholar] [CrossRef
[41] 夏雯, 等. 一种高纯硼粉的制备方法及装置[P]. 中国专利, 201510780933.1, 2015-11-13.
[42] 夏雯, 刘淑凤, 蒋文全, 等. 高纯三溴化硼的制备[J]. 化学试剂, 2014, 36(6): 000569.
[43] Pickering, A.L., Mitterbauer, C., Browning, N.D., et al. (2007) Room Temperature Synthesis of Sur-face-Functionalised Boron Nanoparticles. Chemical Communications, 6, 580. [Google Scholar] [CrossRef] [PubMed]
[44] Si, P.Z., Zhang, M., You, C.Y., et al. (2003) Amorphous Boron Nanoparticles and BN Encapsulating Boron Nano-Peanuts Prepared by Arc-Decomposing Diborane and Nitriding. Journal of Materials Science, 38, 689-692. [Google Scholar] [CrossRef
[45] Parakhonskiy, G. (2012) Synthesis and Investigation of Boron Phases at High Pressures and Temperatures.
[46] Oleksandr, O., Kurakevych, Y.G., Hammouda, T., et al. (2012) Comparison of Solid State Crystallization of Boron Polymorphs at Ambient and High Pressures. High Pressure Research, 32, 30-38. [Google Scholar] [CrossRef
[47] 韩美, 朱心才. 乙硼烷的制备方法[J]. 低温与特气, 1998(2): 35-38.