甘油直接氢解合成1,3-丙二醇催化剂的研究与进展
Research and Progress on Catalysts for Direct Hydrogenolysis of Glycerol to 1,3-Propanediol
DOI: 10.12677/AMC.2020.82004, PDF,  被引量   
作者: 吴晓霖, 晁自胜*, 范金成：长沙理工大学材料科学与工程学院，湖南 长沙
关键词: 甘油；1；3-丙二醇；反应机理；催化剂；Glycerol； 1；3-Propanediol； Reaction Mechanism； Catalyst
摘要: 1,3-丙二醇作为聚酯(PTT)的合成单体之一，在许多领域有着宽阔的应用前景。甘油是合成1,3-丙二醇的原料之一。合成1,3-PDO的方法有很多，最近几年的研究热点是甘油直接氢解一步合成法，这种方法被学者们认同并广泛地研究。本文主要介绍了十余年来甘油氢解生成1,3-PDO的催化剂的研究，对催化剂的类型、载体的性质、催化剂的制备和催化反应条件进行了归纳总结。给出一些我们对催化剂的组分、制备方法的理解以及催化反应的机理。同时分析了今后的研究发展方向。
Abstract: As one of the synthetic monomers of polyester (PTT), 1,3-propanediol has broad application pro-spects in many fields. Glycerol is one of the raw materials for the synthesis of 1,3-propanediol. There are many methods to synthesize 1,3-pdo. In recent years, cerium glycerin is one-step syn-thesis by direct hydrogenolysis. This method is recognized by scholars and studied extensively. In this paper, we mainly introduce the research of catalysts for the hydrogenolysis of glycerol to 1,3-pdo over the past ten years, and summarize the types of catalysts, types of supports, synthesis methods and process conditions of catalysts. Some of our understanding of the components of the catalyst, the preparation method and the mechanism of the catalytic reaction are given. At the same time, the future research direction is analyzed.
文章引用：吴晓霖, 晁自胜, 范金成. 甘油直接氢解合成1,3-丙二醇催化剂的研究与进展[J]. 材料化学前沿, 2020, 8(2): 23-34. https://doi.org/10.12677/AMC.2020.82004

参考文献

[1] 方伟国, 姚小兰, 杨继东, 等. 生物基甘油氢解合成1,3-丙二醇催化剂的研究进展[J]. 分子催化, 2018, 32(6): 96-108.
[2] 周昱, 姚洁, 王公应. 1,3-丙二醇合成工艺研究进展[J]. 天然气化工(C1化学与化工), 2006, 31(1): 66-74.
[3] Drent, E. and Jager, W.W. (2000) Hydrogenolysis of Glycerol. US Patent No. 6080898.
[4] 刘龙杰, 张艳华, 王爱琴, 等. 介孔氧化钨担载Pt催化剂上甘油氢解制备1,3-丙二醇[J]. 催化学报, 2012, 33(8): 1257-1261.
[5] Gong, L., Lu, Y., Ding, Y., et al. (2010) Selective Hydrogenolysis of Glycerol to 1,3-Propanediol over a Pt/WO3/TiO2/SiO2 Catalyst in Aqueous Media. Applied Catalysis A, 390, 119-126.
[Google Scholar] [CrossRef] 
[6] Groll, H.P.A. and George, H. (1936) Process of Converting a Polyhydric Alcohol to a Carbonyl Compound. US Patent No.73266034A.
[7] Priya, S.S., Kumar, V.P., Kantam, M.L., et al. (2015) High Efficiency Conversion of Glycerol to 1,3-Propanediol Using a Novel Platinum-Tungsten Catalyst Supported on SBA-15. Industrial & Engineering Chemistry Research, 54, 9104-9115.
[Google Scholar] [CrossRef] 
[8] 仝庆, 高强, 许波连, 等. 催化甘油选择性氢解制备1,3-丙二醇[J]. 有机化学, 2017, 37(3): 753-758.
[9] 陈英, 陈长林. 还原压力及水对Pt/WO3/ZrO2催化甘油氢解性能的影响[J]. 南京工业大学学报(自然科学版), 2013(3): 45-49.
[10] Wang, C. and Chen, C. (2019) Stabilized Hydro-genolysis of Glycerol to 1,3-Propanediol over Mg Modified Pt/WOx-ZrO2 Catalysts. Reaction Kinetics, Mechanisms and Catalysis, 128, 461-477.
[Google Scholar] [CrossRef] 
[11] 金凯. 甘油氢解制1,3-丙二醇的Pt基催化剂的制备及其性能[D]: [硕士学位论文]. 扬州: 扬州大学, 2017.
[12] Lei, N., Zhao, X., Hou, B., et al. (2019) Effective Hydro-genolysis of Glycerol to 1,3-Propanediol over Metal-Acid Concerted Pt/WOx/Al2O3 Catalysts. ChemCatChem, 11, 3903-3912.
[Google Scholar] [CrossRef] 
[13] 宫能锋, 陈长林. 介孔钨铝复合氧化物载铂催化剂催化甘油氢解反应[J]. 南京工业大学学报(自然科学版), 2018, 40(1): 28-33.
[14] 陈长林, 宋敏洁, 秦丽珍. Pt/HPW/ZrO2催化甘油脱氧制取1,3-丙二醇[J]. 南京工业大学学报(自然科学版), 2011, 33(1): 1-7.
[15] 钱伯章. 将甘油直接氢解成为1,3-丙二醇的新催化剂[J]. 聚酯工业, 2010(5): 46-46.
[16] Wan, J., Shen, S.H., Li, B.D., et al. (2009) Ruthenium Nanoparticles Supported on Carbon Nanotubes for Selective Hydrogenolysis of Glycerol to Glycols. Chemistry Letters, 38, 572-573.
[Google Scholar] [CrossRef] 
[17] Maris, E.P., Ketchie, W.C., Murayama, M., et al. (2007) Glycerol Hydrogenolysis on Carbon-Supported PtRu and AuRu Bimetallic Catalysts. Journal of Catalysis, 251, 281-294.
[Google Scholar] [CrossRef] 
[18] Janampelli, S. and Darbha, S. (2018) Metal Oxide Promoted Hydrodeoxygenation Activity of Platinum in Pt-MOx/Al2O3 Catalysts for Green Diesel Production. Energy & Fuels, 32, 12630-12643.
[Google Scholar] [CrossRef] 
[19] Liu, L., Kawakami, S., Nakagawa, Y., et al. (2019) Highly Active Iridium-Rhenium Catalyst Condensed on Silica Support for Hydrogenolysis of Glycerol to 1,3-Propanediol. Applied Catalysis B: Environmental, 256, Article ID: 117775.
[Google Scholar] [CrossRef] 
[20] 邓澄浩, 冷莉, 周静红. 预处理温度对甘油氢解双金属Ir-Re催化剂性能的影响[J]. 催化学报, 2015, 36(10): 1750-1758.
[21] 陈浩, 陈长林. LiH2PO4改性对铂钨铝催化剂的影响[J]. 南京工业大学学报(自然科学版), 2019, 41(3): 13-19.
[22] 杨超军, 张帆, 雷念. Au促进Pt/WO3催化甘油氢解制1,3-丙二醇[J]. 催化学报, 2018, 39(8): 1366-1372.
[23] 魏瑞平, 肖国民, 牛磊. 一种甘油一步氢解法制备1,3-丙二醇的方法[P]. CN201110292744.1.
[24] 王爱琴, 王佳, 赵晓晨. 双金属催化剂在甘油氢解制备1,3-丙二醇中的应用[P]. CN201410592546.0.
[25] Cai, F., Song, X., Wu, Y., et al. (2017) Selective Hydrogenolysis of Glycerol over Acid-Modified Co-Al Catalysts in a Fixed-Bed Flow Reactor. ACS Sustainable Chemistry & Engi-neering, 6, 110-118.
[Google Scholar] [CrossRef] 
[26] Amada, Y., Watanabe, H., Tamura, M., et al. (2012) Structure of ReOx Clusters Attached on the Ir Metal Surface in Ir-ReOx/SiO2 for the Hydrogenolysis Reaction. The Journal of Physical Chemistry C, 116, 23503-23514.
[27] Priya, S.S., Bhanuchander, P., Kumar, V.P., et al. (2016) Activity and Selectivity of Platinum-Copper Bimetallic Catalysts Supported on Mordenite for Glycerol Hydrogen-olysis to 1,3-Propanediol. Industrial & Engineering Chemistry Research, 56, 11065-11074.
[Google Scholar] [CrossRef] 
[28] Liu, L., Asano, T., Nakagawa, Y., et al. (2019) Selective Hy-drogenolysis of Glycerol to 1,3-Propanediol over Rhenium Oxide-Modified Iridium Nanoparticles Coating Rutile Titania Support. ACS Catalysis, 9, 10913-10930.
[Google Scholar] [CrossRef] 
[29] Drent, E. and Jager, W.W. (2000) Hydrogenolysis of Glycerol, US. 6080898.
[30] Wang, K., Hawley, M.C. and DeAthos, S.J. (2003) Conversion of Glycerol to 1,3-Propanediol via Selective Dehydroxylation. Industrial & Engineering Chemistry Research, 42, 2913-2923.
[Google Scholar] [CrossRef] 
[31] Chaminand, J., Djakovitch, L.A., Gallezot, P., et al. (2004) Glycerol Hydrogenolysis on Heterogeneous Catalysts. Green Chemistry, 6, 359-361.
[Google Scholar] [CrossRef] 
[32] García-Fernández, S., Gandarias, I., Requies, J., et al. (2015) New Ap-proaches to the Pt/WOx/Al2O3 Catalytic System Behavior for the Selective Glycerol Hydrogenolysis to 1,3-Propanediol. Journal of Catalysis, 323, 65-75.
[Google Scholar] [CrossRef] 
[33] Amada, Y., Shinmi, Y., Koso, S., et al. (2011) Reaction Mechanism of the Glycerol Hydrogenolysis to 1,3-Propanediol over Ir-ReOx /SiO2 Catalyst. Applied Catalysis B: Environmental, 105, 117-127.
[34] Feng, S., Zhao, B., Liu, L., et al. (2017) Platinum Supported on WO3-Doped Aluminosilicate: A Highly Efficient Catalyst for Selective Hydrogenolysis of Glycerol to 1,3-Propanediol. Industrial & Engineering Chemistry Research, 56, 11065-11074.
[Google Scholar] [CrossRef]