金属有机骨架化合物的研究进展
Research Progress of Metal-Organic Skeleton Compounds
DOI: 10.12677/MS.2021.118110, PDF,  被引量    科研立项经费支持
作者: 王新芳, 李文博*, 牟 芬：昌吉学院，新疆 昌吉；王新荣：新特能源股份有限公司，新疆 乌鲁木齐
关键词: 金属有机骨架化合物；合成方法；影响因素；性能；Metal-Organic Skeleton Compounds； Synthetic Methods； Influencing Factors； Properties
摘要: MOFs (金属有机骨架化合物)因其可设计的结构、可配置的拓扑结构、可调谐功能、易功能化的腔体、超高的孔隙率和比表面积等特性，使它在化学、生物和工业领域的应用中展现出了巨大的潜力。本文总结了MOFs合成方法及其优缺点，并总结了其影响因素，以便研究从预期目标去获得特定MOFs结构和应用性能，同时列举了金属有机骨架化合物潜在性能方面的研究进展，并对MOFs的发展前景作了展望。
Abstract: MOFs (metal-organic skeleton compounds) have shown great potential in chemical, biological and industrial applications due to their designable structure, configurable topological structure, tunable function, easily functionalized cavity, ultra-high porosity and specific surface area, etc. In this paper, the synthesis methods of MOFs, their advantages and disadvantages are summarized, and the influencing factors are summarized, so as to obtain the specific structure and application properties of MOFs from the expected target. At the same time, the research progress in the potential properties of metal-organic framework compounds is listed, and the development prospect of MOFs is prospected.
文章引用：王新芳, 王新荣, 李文博, 牟芬. 金属有机骨架化合物的研究进展[J]. 材料科学, 2021, 11(8): 950-957. https://doi.org/10.12677/MS.2021.118110

参考文献

[1] Kökçam-Demir, Ü., Goldman, A., Esrafifili, L., Gharib, M., Morsali, A., Weingart, O. and Janiak, C. (2020) Coordina-tively Unsaturated Metal Sites (Open Metal Sites) in Metal-Organic Frameworks: Design and Applications. Chemical Society Reviews, 49, 2751-2798. [Google Scholar] [CrossRef] 
[2] Zhou, H.C., Long, J.R. and Yaghi, O.M. (2012) Metal-Organic Frameworks: Design and Application. Chemical Reviews, 112, 673-674. [Google Scholar] [CrossRef] [PubMed]
[3] Bai, Y., Dou, Y.B., Xie, L.H., Rutledge, W., Li, J.R. and Zhou, H.C. (2016) ChemInform Abstract: Zr-Based Metal-Organic Frameworks: Design, Synthesis, Structure, and Applications. Chemical Society Reviews, 45, 2327-2367. [Google Scholar] [CrossRef] 
[4] Wang, Z., Sun, Q.Q., Liu, B., Kuang, Y., Gulzar, A., He, F., Gai, S.L., Yang, P.P. and Lin, J. (2021) Recent Advances in Porphyrin-Based MOFs for Cancer Therapy and Diagnosis Therapy. Coordination Chemistry Reviews, 439, Article ID: 213945. [Google Scholar] [CrossRef] 
[5] Li, H.L., Eddaoudi, M. and Yaghi, O.M. (1999) Design and Synthesis of an Exceptionally Stable and Highly Porous Met-al-Organic Framework. Nature, 402, 276-279. [Google Scholar] [CrossRef] 
[6] Eddaoudi, M., Kim, J. and Yaghi, O.M. (2002) Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage. Science, 295, 469-472. [Google Scholar] [CrossRef] [PubMed]
[7] Zhong, D.C., Lu, W.G., Jiang, L., Feng, X.L. and Lu, T.B. (2010) Three Coordination Polymers Based on 1H-Tetrazole (HTz) Generated via in Situ Decarboxylation: Synthesis, Structures, and Selective Gas Adsorption Properties. Crystal Growth & Design, 10, 739-746. [Google Scholar] [CrossRef] 
[8] Gole, B., Bar, A.K. and Mukherjee, P.S. (2011) Fluorescent Metal-Organic Framework for Selective Sensing of Nitroaromatic Explosives. Chemical Communications, 47, 12137-12139. [Google Scholar] [CrossRef] [PubMed]
[9] Shi, P.F., Hu, H.C. and Zhang, Z.Y. (2015) Heteromet-al-Organic Frameworks as Highly Sensitive and Highly Selective Luminescent Probes to Detect I Ions in Aqueous Solu-tions. Chemical Communications, 51, 3985-3988. [Google Scholar] [CrossRef] 
[10] Zou, R.Q., Bu, X.H. and Zhang, R.H. (2004) Novel Eclipsed 2D Cad-mium(II) Coordination Polymers with Open-Channel Structure Constructed from Terephthalate and 3-(2-pyridyl)pyrazole: Crystal Structures, Emission Properties, and Inclusion of Guest Molecules. Inorganic Chemistry, 43, 5382-5386. [Google Scholar] [CrossRef] [PubMed]
[11] Hwang, Y.K., Chang, J.S. and Park, S.E. (2005) Micro-wave Fabrication of MFI Zeolite Crystals with a Fibrous Morphology and Their Applications. Angewandte Chemie In-ternational Edition, 44, 556-560. [Google Scholar] [CrossRef] [PubMed]
[12] Wang, X.Y., Wang, Z.M. and Gao, S.A. (2007) Pillared Layer MOF with Anion-Tunable Magnetic Properties and Photochemical [2 + 2] Cycloaddition. Chemical Communications, 11, 1127-1129. [Google Scholar] [CrossRef] [PubMed]
[13] Müller, U., Lobree, L. and Hesse, M. (1997) Process for the Epoxidation of an Organic Compound with Oxygen or an Oxygen-Delivering Compounds Using Catalysts Containing Metal-Organic Frame-Work Materials. US 10/157494.
[14] Lia, X., Zhang, F. and Yang, Y.Y. (2019) An Instant Re-used Luminescent Mixed Matrix Membrane Sensor for Convenient Phenolic Nitro-Explosives Detection. Journal of Photochemistry and Photobiology A: Chemistry, 370, 51-57. [Google Scholar] [CrossRef] 
[15] Sun, D.R. and Li, Z.H. (2016) Double-Solvent Method to Pd Nanoclusters Encapsulated inside the Cavity of NH2-Uio-66(Zr) for Efficient Visible-Light-Promoted Suzuki Cou-pling Reaction. The Journal of Physical Chemistry C, 120, 19744-19750. [Google Scholar] [CrossRef] 
[16] Wang, K.C., Feng, D.W., Liu, T.F., Su, J., Yuan, S., Chen, Y.P., Bosch, M., Zou, X.D. and Zhou, H.C. (2014) A Series of Highly Stable Mesoporous Metalloporphyrin Fe-MOFs. Journal of the American Chemical Society, 136, 13983-13986. [Google Scholar] [CrossRef] [PubMed]
[17] Hughes, J.T., Sava, D.F. and Nenoff, T.M. (2013) Thermochemical Evi-dence for Strong Iodine Chemisorption by ZIF-8. Journal of the American Chemical Society, 135, 16256-16259. [Google Scholar] [CrossRef] [PubMed]
[18] Jihyun, A., Steven, J.G. and Nathaniel, L.R. (2009) Cation-Triggered Drug Release from a Porous Zinc-Adeninate Metal-Organic Framework. Journal of the American Chemical Society, 131, 8376-8377. [Google Scholar] [CrossRef] [PubMed]

为你推荐