钯钇合金净化器的氢-氦分离性能
Performance of Palladium Yttrium Alloy Purifier in Hydrogen and Helium Separation
摘要: 以钯-8%钇合金为净化器,进行了氢–氦分离性能研究。结果表明,该净化器具有操作模式简单、体积小、批处理能力大、工作温度低等特点,净化器的日处理能力约20 mol,经循环分离处理后,氢–氦混合气得到了较好的分离,氦气中氢气含量和氢气中氦气含量均低至0.1%。
Abstract: Researches on hydrogen and helium separation performance were done at Pa-8%Y alloy purifier. The result shows that the purifier has many advantages such as simple operator schema, low volume, great batch processing ability and low operating temperature. The handling capacity of purifier is 20 mol/day. The hydrogen concentration in helium gas and the helium concentration in hydrogen gas are both lower than 0.1% after circulating separate process from hydrogen and helium mixture.
文章引用:宋智蓉, 熊义富, 敬文勇. 钯钇合金净化器的氢-氦分离性能[J]. 核科学与技术, 2022, 10(4): 219-224. https://doi.org/10.12677/NST.2022.104023

参考文献

[1] Tong, H.D., Gielens, F.C., Gardeniers, J.G.E., Jansen, H.V., Van Rijin, C.J.M., Elwenspoek, M.C. and Nijdam, W. (2004) Microfabricated Palladium-Silver Alloy Membranes and Their Application in Hydrogen Separation. Journal of Chemical Engineering Science, 43, 4182-4187. [Google Scholar] [CrossRef
[2] Ryia, S.K., Parka, J.S., Kimb, S.H., Kimc, D.W. and Kimc, H.K. (2009) Low Temperature Diffusion Bonding of Pd-Based Composite Mem-branes with Metallic Module for Hydrogen Separation. Journal of Membrane Science, 326, 589-594. [Google Scholar] [CrossRef
[3] Pizzi, D., Worth, R., Baschetti, M.G., Sarti, G. and Noda, K.I. (2008) Hydrogen Permeability of 2.5 μm Palladium-Silver Membranes Deposited on Ceramic Supports. Journal of Membrane Science, 325, 446-453. [Google Scholar] [CrossRef
[4] Ma, Y.H., Mardilovich, I. and Engwall, E. (2003) Thin Compo-site Palladium and Palladium / Alloy Membranes Forhydrogen Separation. Annals of the New York Academy of Science, 984, 346-360. [Google Scholar] [CrossRef] [PubMed]
[5] Sieverts, A. and Zapf, G. (1935) Solubility of H and D in Soild Pd(I). Zeitschrift für Physikalische Chemie, 174, 359-364. [Google Scholar] [CrossRef
[6] Holleck, G.C. (1970) Diffusion and Solubility of Hydrogen in Pal-ladium and Palladium—Sliver Alloys. Journal of Physical Chemistry, 74, 503-511. [Google Scholar] [CrossRef
[7] Rosset, A.J. (1960) Diffusion of Hydrogen through Palladium Mem-branes. Industrial and Engineering Chemistry, 52, 525-528. [Google Scholar] [CrossRef
[8] Ward, T.L. and Dao, T. (1999) Model of Hydrogen Permeation Behavior in Palladium Membrane. Journal of Membrane Science, 153, 211-231. [Google Scholar] [CrossRef
[9] Zheng, W. and Wu, L. (2000) Preparation and Pore Size Shrinkage of Palladium-Ceramic Composite Membrane by Electroless Plating under Hydrothermal conditions. Materials Science and Engineering A, 283, 122-125. [Google Scholar] [CrossRef
[10] Rothernberger, K.S., Cugini, A.V., Howard, B.H., Killmeryer, R.P., Michael, V.C., Bryan, D.M., Robert, M.E., Felipe, B., Ivan, P.M. and Ma, Y.H. (2004) High Pressure Hydrogen Permeance of Porous Stainless Steel Coated with a Thin Palladium Film via Electroless Plating. Journal of Membrane Science, 244, 55-68. [Google Scholar] [CrossRef
[11] Chen, S.C., Tu, G.C., Caryat, C.Y., Hung, C.A. and Rei, M.H. (2008) Preparation of Palladium Membrane Byelectroplating on AISI 316Lporous Stainless Steel Supports and Its Use for Methanol steam Reformer. Journal of Membrane Science, 314, 5-14. [Google Scholar] [CrossRef
[12] Nam, S.E. and Lee, K.H. (2001) Hydrogen Separation by Pd Alloy Composite Membranes: Introduction of Diffusion Barrier. Journal of Membrane Science, 192, 177-185. [Google Scholar] [CrossRef
[13] Xie, D.L., Adris, A.M., Lim, C.J. and Grance, J.R. (2009) Test on a Modular Fluidized Bed Membrane Reactor Forautothermal Steam Methane Reforming. Acta Energiae Solaris Sinica, 30, 704-707.
[14] Chen, Z., Grace, J.R., Lim, C.J. and Li, A. (2007) Experimental Studies of Pure Hydrogen Production in a Commercialized Fluidized Bed Membrane Reactor with SMR and ATR Catalysts. International Journal of Hydrogen Energy, 32, 2359-2366. [Google Scholar] [CrossRef
[15] Xie, D.L., Grace, J.R. and Lim, C. (2006) Development of an Internally Circulating Fluidized Bed Membrane Reactor for Hydrogen Production from Natural Gas. Journal of Wuhan University of Technology, 28, 252-257.
[16] Mahecha-Botero, A., Boyd, T., Gu-lamhusein, A., Comyn, N., Jim Lim, C., Grace, J.R., et al. (2008) Pure Hydrogen Generation in a Fluidized-Bed Mem-brane Reactor: Experimental Findings. Chemical Engineering Science, 63, 2752-2762. [Google Scholar] [CrossRef
[17] Shirasakia, Y., Tsunekia, T., Otaa, Y., Yasuda, I., Tachibana, S., Nakajima, H., et al. (2009) Development of Membrane Reformer System for Highly Efficient Hydrogen Production from Natural Gas. International Journal of Hydrogen Energy, 34, 4482-4487. [Google Scholar] [CrossRef
[18] Patil, C.S., Annaland, M. and Kuipers, J.A.M. (2007) Fluid-ised Bed Membrane Reactor for Ultrapure Hydrogenproduction via Methane Steam Reforming: Experimental Demon-stration and Model Validation. Chemical Engineering Science, 62, 2989-2930. [Google Scholar] [CrossRef