硼同位素分离研究进展
Research Progress in Boron Isotope Separation
摘要: 随着科技的不断发展,硼同位素的需求越来越大。目前,硼同位素的生产技术还主要掌握在欧美等国,我国尚不能实现大规模的工业化生产。本文对目前分离硼同位素的四种方法:化学交换精馏法、低温精馏法、吸附分离法、激光分离法,从分离原理、分离方法、分离物质等方面进行了研究探讨。发现目前只有化学交换精馏法及低温精馏法存在工业化的可能,其他方法仍然需要一定的优化才能在工业上进行应用。
Abstract: With the continuous development of science and technology, the demand for boron isotopes is increasing. Currently, the production technology of boron isotopes is still mainly mastered in Europe and the United States, and China is still unable to achieve large-scale industrial production. In this paper, four methods for separating boron isotopes, namely chemical exchange distillation, low-temperature distillation, adsorption separation, and laser separation, have been studied and discussed in terms of separation principles, separation methods, and separation of substances. It was found that only chemical exchange distillation and low-temperature distillation currently have the possibility of industrialization, while other methods still require some optimization to be applied in industry.
文章引用:周贝霖, 胡石林. 硼同位素分离研究进展[J]. 化学工程与技术, 2023, 13(3): 161-173. https://doi.org/10.12677/HJCET.2023.133019

参考文献

[1] 郑学家. 核工业用硼化物[M]. 北京: 化学工业出版社, 2015: 1-3.
[2] Jugdeep, K. and Martin, R. (1995) Boron Isotope Analysis. A Review. Analyst, 120, 1301-1307. [Google Scholar] [CrossRef
[3] 包丽. 离子交换色谱法分离硼同位素的研究[D]: [硕士学位论文]. 天津: 天津大学, 2016.
[4] Rasouli, F. and Masoudi, S. (2015) A Study on the Optimum Fast Neutron Flux for Boron Neutron Capture Therapy of deep-Seated Tumors. Applied Radiation and Isotopes, 96, 45-51. [Google Scholar] [CrossRef] [PubMed]
[5] Buszka, P.M., Fitzpatrick, J., Watson, L.R., et al. (2007) Evaluation of Ground-Water and Boron Sources by Use of Boron Stable-Isotope Ratios, Tritium, and Selected Water-Chemistry-Constituents Near Beverly Shores, Northwestern Indiana, 2004. Geological Survey Scientific In-vestigations Report 2007-5166, U.S. Geological Survey, Reston, 46 p. [Google Scholar] [CrossRef
[6] 方治文. 高纯三氯化硼-11的制备方法[P]. 中国专利, 103950947A. 2015-09-09.
[7] Conn, A.L. and Wolf, J.E. (1958) Large-Scale Separation of Boron Isotopes. In-dustrial Engineering Chemistry, 50, 1231-1234. [Google Scholar] [CrossRef
[8] Song, S., Mu, Y., Li, X. and Bai, P. (2010) Advances in Boron-10 Isotope Separation by Chemical Exchange Distillation. Annals of Nu-clear Energy, 37, 1-4. [Google Scholar] [CrossRef
[9] Palko, A.A. and Drury, J.S. (1967) Fractionation of Boron Isotopes between boron Trifluoride and Its Molecular Addition Compounds. The Journal of Chemical Physics, 47, 2561-2566. [Google Scholar] [CrossRef
[10] Wu, X., Bai, P., Guo, X. and He, N. (2014) 2,4-Difluoro Anisole: A Promising Complexing Agent for Boron Isotopes Separation by Chemical Exchange Reaction and Distillation. Journal of Radioanalytical and Nuclear Chemistry, 300, 897-902. [Google Scholar] [CrossRef
[11] Herbst, R.S. and McCandless, F.P. (1994) Improved Donors for the Separation of the Boron Isotopes by Gas-Liquid Exchange Reactions. Separation Science and Technology, 29, 1293-1310. [Google Scholar] [CrossRef
[12] Karl, E.H. (1995) Concentration of Iso-topes. BP: 736459.
[13] Saxema, S.C., Gupta, A.R., Poncha, R.P., et al. (1961) Enrichment of Bl0 by Chemical Exchange. IndResearch, 20, 393-397.
[14] 谭国锋. 硼同位素分离的研究[D]: [硕士学位论文]. 天津: 天津大学, 2004.
[15] 王辉. 化学交换与精馏法分离硼同位素中试实验装置和分析装置的设计[D]: [硕士学位论文]. 天津: 天津大学, 2006.
[16] 庞宝琳. 苯甲醚除杂的模拟与实验研究[D]: [硕士学位论文]. 天津: 天津大学, 2007.
[17] 史志强. 用于硼同位素分离过程的填料的研究[D]: [硕士学位论文]. 天津: 天津大学, 2009.
[18] 张鸾. 吸附法脱除苯甲醚中微量水的研究[D]: [硕士学位论文]. 天津: 天津大学, 2013.
[19] 何娜娜. 化学交换精馏分离硼同位素副反应研究[D]: [硕士学位论文]. 天津: 天津大学, 2014.
[20] 周娇娇. 三氟化硼∙苯甲醚络合反应过程研究[D]: [硕士学位论文]. 天津: 天津大学, 2016.
[21] 唐银. 硼同位素分离过程检测分析技术研究[D]: [博士学位论文]. 天津: 天津大学, 2018.
[22] Sevryugova, N.N., Uvarov, O.V. and Zhavoronkov, N.M. (1960) Separation of the Stable Isotopes of Boron. Journal of Nuclear Energy, 13, 374-379.
[23] Sevryugova, N., Uvarov, O. and Zhavoronkov, N. (1960) Separation Factors of Boron Isotopes in the Equilibrium Vaporization of BF3. Journal of Nuclear Energy, 9, 110-125.
[24] Amirkhanova, I.B., Borisov, A.V., Gverdtsueli, I.G. and Karamyan, A.T. (1966) Relative Difference of The Vapour Pressures of 11BF3, and 10BF3. Journal of Nuclear Energy Parts, 20, 591-597. [Google Scholar] [CrossRef
[25] 周帆. 硼同位素分离过程的计算化学研究[D]: [硕士学位论文]. 天津: 天津大学, 2018.
[26] Yoneda, Y., Uchijima, T. and Makishima, S. (1959) Separation of Boron Isotopes by Ion Ex-Change. The Journal of Physical Chemistry A, 63, 2057-2058. [Google Scholar] [CrossRef
[27] Kakihana, H., Kotaka, M., Satoh, S., et al. (1977) Fundamental Studies on the Ion-Exchange Separation of Boron ISOTOPES. Bulletin of the Chemical Society of Japan, 50, 158-163. [Google Scholar] [CrossRef
[28] Sharma, B.K., Rajamani, P. and Mathur, P.K. (1977) Use of Type-II Strong Base Anion Exchange Resins for Ion Exchange Chromatographic Separation of Isotopes of Boron. Indian Journal of Chemical Technology, 4, 308-316.
[29] Sakuma, Y., Aida, M., Okamoto, M., et al. (1980) Boron Isotope Separation by Ion Exchange Chromatography Using Weakly Basic Anionexchange Resin. Bulletin of the Chemical Society of Japan, 53, 1860-1863. [Google Scholar] [CrossRef
[30] Aida, M., Fujii, Y. and Okamoto, M. (1980) Chromatographic En-richment of 10B by Usingweak-Base Anion-Exchange Resin. Separation Science and Technology, 2, 1643-1654.
[31] Mardan, A. (1997) Enrichment of Boron-10 by Inverse-Frontal Chromatography Using Quater-nized 4-Vinylpyridine- Divinylbenzene Anion-Exchange Resin. Separation Science and Technology, 32, 2115-2125. [Google Scholar] [CrossRef
[32] Guan, Z., Lv, J., Bai, P. and Guo, X.H. (2016) Boron Re-moval from Aqueous Solutions by Adsorption: A Review. Desalination, 383, 29-37. [Google Scholar] [CrossRef
[33] Oi, T., Shimazaki, H., Ishii, R. and Hosoe, M. (1997) Boron Isotope Fractionation in Liquid Chroma-Tography with Boron-Specific Resins as Column Packing Material. Sepa-ration Science and Technology, 32, 1821-1834. [Google Scholar] [CrossRef
[34] Sonoda, A., Makita, Y. and Hirotsu, T. (2008) Boron Iso-tope Fractionation in Column Chro-matography with Glucamine Type Fibers. Journal of Nuclear Science and Technology, 12, 117-121. [Google Scholar] [CrossRef
[35] Lyu, J., Liu, H., Zhang, J., et al. (2017) Metal-Organic Frameworks (MOFs) as Highly Efficient Agents for Boron Removal and Boron Isotope Separation. RSC Advances, 7, 16022-16026. [Google Scholar] [CrossRef
[36] Chen, T., Wang, Q., Lyu, J., et al. (2020) Boron Removal and Reclamation by Magnetic Magnetite (Fe3O4) Nanoparticle: An Adsorption and Isotopic Separation Study. Separation and Purification Technology, 23, 1115930-115939. [Google Scholar] [CrossRef
[37] Xiao, J., Xiao, Y., Liu, C., et al. (2009) Boron Isotopic Fractionation during Incorporation of Boron into Mg(OH)2. Chinese Science Bulletin, 54, 3090-3100. [Google Scholar] [CrossRef
[38] Lemarchand, E., Schott, J. and Gaillardet, J. (2005) Boron Isotopic Fractionation Related to Boron Sorption on Humic Acid and the Structure of Surface Complexes Formed. Geochimica et Cosmochimica Acta, 69, 3519-3533. [Google Scholar] [CrossRef
[39] Wang, Q., Chen, T., Bai, P., Lyu, J. and Guo, X. (2021) Fe3O4-Loaded Ion Exchange Resin for Chromatographic Separation of Boron Isotopes: Experiment and Numerical Simulation. Chemical Engineering Research and Design, 171, 358-366. [Google Scholar] [CrossRef
[40] Greenland, P.T. (1990) Laser Isotope Separation. Contem-porary Physics, 31, 405-424. [Google Scholar] [CrossRef
[41] Ambartsumyan, R.V., Letokhov, V.S., Ryabov, E.A., et al. (1974) Chekalin Isotopically Selective Chemical Reaction of BCl3 Molecules in Powerful Infrared Laser Field. Soviet Physics, JETP, 20, 273-275.
[42] Ambartsumyan, R.V., Chekalin, N.V., Letokhov, V.S., et al. (1976) Separation of Isotopes in a Strong Infrared Laser Field. Soviet Journal of Quantum Electronics, 6, 437-441. [Google Scholar] [CrossRef
[43] Lyman, J.L. and Rockwood, S.D. (1976) En-richment of Boron, Carbon and Silicon Isotopes by Multiple-Photon Absorption of 10.6-μm Laser Radiation. Journal of Applied Physics, 47, 595-601. [Google Scholar] [CrossRef
[44] Freund, S.M. and Ritter, J.J. (1975) CO2 Tea Laser-Induced Photochemical Enrichment of Boron Isotopes. Chemical Physics Letters, 32, 255-260. [Google Scholar] [CrossRef
[45] Reed, J.J., James, M.T., Coran, C.L., et al. (1984) Method of Separating Boron Isotopes. US Patent No. 4447303.
[46] Suzuki, K. (1995) Separation of Boron Isotopes by Infrared Laser. Proceedings of the Sixth International Symposium on Advanced Nuclear Energy Research: Inno-vative Laser Technologies in Nuclear Energy, Mito, 23-25 March 1994, 1019-1026.
[47] Pronko, P.P., VanRompay, P.A., Zhang, Z., et al. (1999) Isotope Enrichment in Laser-Ablation Plumes and Commensurately Deposited Thin Films. Physical Review Letters, 83, 2596-2599. [Google Scholar] [CrossRef
[48] Hashidaa, M., Izawab, Y., Nagaya, Y. and Ayabe, M. (1999) FEL Multiphoton Dissociation and Isotope Separation of Boron. Nuclear Instruments and Methods in Physics Re-search A: Accelerators, Spectrometers, Detectors and Associated Equipment, 429, 485-488. [Google Scholar] [CrossRef
[49] 齐鑫. 激光光谱法分离硼同位素[J]. 山东化工, 2020, 49(15): 108-110.
[50] Lyakhov, K.A. and Pechen, A.N. (2020) CO2 Laser System Design for Effcient Boron Iso-tope Separation by the Method of Selective Laser-Assisted Retardation of Condensation. Applied Physics B, 260, Article No. 141. [Google Scholar] [CrossRef