卷烟热裂解香料及其热解规律研究进展
Research Progress on Cigarette Pyrolysis Spices and Pyrolysis Principle
DOI: 10.12677/HJFNS.2023.122009, PDF,    科研立项经费支持
作者: 刘 浩, 周冰莹, 吴泽宇, 惠爱玲, 张文成*:合肥工业大学食品与生物工程学院,农产品生物化工教育部工程研究中心,安徽 合肥;胡永华, 徐志强:安徽中烟工业有限责任公司技术中心,安徽 合肥
关键词: 烟草香料裂解结构演变动力学 Tobacco Flavoring Cracking Structural Evolution Kinetics
摘要: 基于热裂解是在惰性气氛下使反应物发生热裂解并生成可冷凝挥发组分(热解油)、不可冷凝热解气和固体产物(热解炭),本文重点探讨加热卷烟裂解、燃烧过程中结构演变规律、产物的生成机理和调控机制,总结了许多具有综合机理方案的动力学模型,如Coats-Redfern模型、双高斯分布活化能模型(DG-DAEM)和Toba-CPD模型。通过对烟草热解机理进行研究,深入理解烟草原料到生物油的转化路径,并对烟草香味物质提取与分离纯化技术的发展前景进行了展望。
Abstract: Pyrolysis is the thermal cracking of reactants in an inert atmosphere (under low oxygen atmosphere) and gener-ates condensable volatile fraction (pyrolysis oil), non-condensable pyrolysis gas and solid products (pyrolysis carbon), this paper synthesizes the current status of domestic and foreign research, fo-cusing on the structure evolution law, product generation mechanism and regulation mechanism during the pyrolysis and combustion of heated cigarettes, and provides an in-depth understanding of the transformation path from tobacco raw materials to bio-oil through the study of tobacco py-rolysis mechanism, and provides an outlook on the development prospect of tobacco aroma sub-stance extraction and separation and purification technology.
文章引用:刘浩, 周冰莹, 胡永华, 徐志强, 吴泽宇, 惠爱玲, 张文成. 卷烟热裂解香料及其热解规律研究进展[J]. 食品与营养科学, 2023, 12(2): 66-73. https://doi.org/10.12677/HJFNS.2023.122009

参考文献

[1] 国家统计局. 家数据年度数据——主要农作物产品产量[EB/OL].
https://data.stats.gov.cn/easyquery.htm?cn=C01&zb=A0D0F&sj=2021, 2023-02-05.
[2] 杨彩艳, 莫丽娟, 孙佩玲. 烟草化学成分及生物活性研究现状[J]. 天然产物研究与开发, 2016, 28(10): 1657-1663, 1621.
[3] 乔学义, 王兵, 马宇平, 等. 烤烟烟叶质量风格特色感官评价方法的建立与应用[J]. 烟草科技, 2014(9): 5-9.
[4] Chen, J., He, X., Zhang, X., et al. (2021) The Applicability of Different Tobacco Types to Heated Tobacco Products. Industrial Crops and Products, 168, Article ID: 113579. [Google Scholar] [CrossRef
[5] 赵璐, 王丙武, 宋中邦, 高玉龙, 李文正, 李梅云, 隋学艺, 吴兴富, 焦芳婵, 尚善斋, 汤建国, 李永平. 基于感官评价的加热不燃烧卷烟原料品种(系)筛选[J]. 烟草科技, 2020, 53(1): 21-28
[6] Yin, F., Karangwa, E., Song, S., et al. (2019) Contribution of Tobacco Composition Compounds to Characteristic Aroma of Chinese Faint-Scent Cigarettes through Chromatography Analysis and Partial Least Squares Regression. Journal of Chromatography B, 1105, 217-227. [Google Scholar] [CrossRef] [PubMed]
[7] Soares, F.L.F., Marcelo, M.C.A., Dias, J.C., et al. (2020) Chemosensory Aerosol Assessment of Key Attributes for Tobacco Products. Journal of Chemometrics, 34, e3297. [Google Scholar] [CrossRef
[8] Borgerding, M.F., Bodnar, J.A., Chung, H.L., et al. (1998) Chemical and Biological Studies of a New Cigarette That Primarily Heats Tobacco: Part 1. Chemical Composition of Mainstream Smoke. Food and Chemical Toxicology, 36, 169-182. [Google Scholar] [CrossRef
[9] Cosmai, L., Summo, C., Caponio, F., Paradiso, V.M. and Gomes, T. (2013) Influence of the Thermal Stabilization Process on the Volatile Profile of Canned Tomato-Based Food. Journal of Food Science, 78, 1865-1870. [Google Scholar] [CrossRef] [PubMed]
[10] 刘秀华, 钟志京, 谢云, 等. 烟丝热解气体产物中有机物的分析[J]. 中国烟草科学, 2007(6): 13-16+21.
[11] 罗昌荣, 张乾, 印黔黔, 曾令杰, 王兵, 顾文博, 谢雯燕. 多步逐级裂解技术研究卷烟燃时香味成分形成与温度之间的关系[J]. 食品与生物技术学报, 2022, 41(12): 96-104.
[12] Sanders, E.B., Goldsmith, A.I. and Seeman, J.I. (2003) A Model that Distinguishes the Pyrolysis of D-Glucose, D-Fruc- tose and Sucrose from That of Cellulose. Application to the Understanding of Cigarette Smoke Formation. Journal of Analytical and Applied Pyrolysis, 66, 29-50. [Google Scholar] [CrossRef
[13] 李巧灵, 刘江生, 邓小华, 等. 烟草热解燃烧过程香味成分的释放变化[J]. 烟草科技, 2014, 328(11): 62-66.
[14] Baker, R.R. (1987) A Review of Pyrolysis Studies to Unrav-el Reaction Steps in Burning Tobacco. Journal of Analytical and Applied Pyrolysis, 11, 555-573. [Google Scholar] [CrossRef
[15] 李巧灵, 陈昆焱, 刘泽春, 等. 基于热重的烟草热解差异度分析[J]. 烟草科技, 2017, 50(8): 75-79+102. [Google Scholar] [CrossRef
[16] 秦国鑫, 李斌, 鲁端峰, 等. 烟草生物质燃烧特性与机理研究[J]. 烟草科技, 2015, 48(1): 76-81. [Google Scholar] [CrossRef
[17] 童保云, 张晓宇, 孔俊, 朱青林, 胡永华. 烤烟烟叶叶片及其烟梗的热分解过程和动力学[J]. 烟草科技, 2013(12): 54-58.
[18] Li, X., Zhao, Q., Han, M., et al. (2022) Pyrolysis Characteristics and Kinetic Analysis of Tobacco Stem Pretreated with Different Solvents. Biomass Conversion and Biorefinery, 1-15. [Google Scholar] [CrossRef
[19] 王昭, 戴亚, 马扩彦, 等. 基于分布活化能模型的烟草燃烧动力学特性研究[J]. 烟草科技, 2016, 49(12): 71-78.
[20] Wu, W., Mei, Y., Zhang, L., Liu, R. and Cai, J. (2015) Kinetics and Reaction Chemistry of Pyrolysis and Combustion of Tobacco Waste. Fuel, 156, 71-80. [Google Scholar] [CrossRef
[21] Friedman, H.L. (2010) Kinetics of Thermal Degradation of Char-Forming Plastics from Thermogravimetry. Application to a Phenolic Plastic. Journal of Polymer Science Part C: Polymer Symposia, 6, 183-195. [Google Scholar] [CrossRef
[22] Fan, H., Zhang, Y., Su, Z. and Wang, B. (2017) A Dynamic Math-ematical Model of a Coal Fired Once-Through Boiler-Turbine Unit. Applied Energy, 189, 654-666. [Google Scholar] [CrossRef
[23] Chen, Z.H., Zhu, Q.J., Wang, X., Xiao, B. and Liu, S. (2015) Pyrolysis Behaviors and Kinetic Studies on Eucalyptus Residues Using Thermogravimetric Analysis. Energy Conversion and Management, 105, 251-259. [Google Scholar] [CrossRef
[24] Xing, J., Wang, H., Luo, K., Wang, S., Bai, Y. and Fan, J. (2019) Predictive Single-Step Kinetic Model of Biomass Devolatilization for CFD Applications: A Comparison Study of Empirical Correlations (EC), Artificial Neural Networks (ANN) and Random Forest (RF). Renewable Energy, 136, 104-114. [Google Scholar] [CrossRef
[25] 邢江宽, 王海鸥, 罗坤, 等. 预测生物质热解动力学参数的随机森林模型[J]. 浙江大学学报(工学版), 2019, 53(3): 605-612.
[26] 范兴, 李博宇, 杨蕾, 等. 烤烟烟梗原料化学成分的差异[J]. 烟草科技, 2022, 55(11): 46-57.
[27] Francis, M.J.O. and Allcock, C. (1969) Geraniol β-D-Glucoside; Occurrence and Synthesis in Rose Flowers. Phytochemistry, 8, 1339-1347. [Google Scholar] [CrossRef
[28] Yang, L.Y., Wang, L.T., Ma, J.H., Li, J.Y. and Gong, M. (2017) Effects of Light Quality on Growth and Development, Photosynthetic Characteristics and Content of Carbohy-drates in Tobacco (Nicotiana tabacum L.) Plants. Photosynthetica, 55, 467-477. [Google Scholar] [CrossRef
[29] 黄沛. 烤烟化学成分与感官评吸的相关分析[J]. 安徽农业科学, 2015, 43(28): 288-290. [Google Scholar] [CrossRef
[30] 杨滢. 烟草纤维素结构及燃烧热解特性研究[D]: [硕士学位论文]. 合肥: 中国科学技术大学, 2017.
[31] Boulanger, R. and Crouzet, J. (2000) Free and Bound Flavour Components of Amazonian Fruits: 2. Cupuacu Volatile Compounds. Flavour and Fragrance Journal, 15, 251-257. [Google Scholar] [CrossRef
[32] Wang, D., Yoshimura, T., Kubota, K. and Kobayashi, A. (2000) Analysis of Glycosidically Bound Aroma Precursors in Tea Leaves. 1. Qualitative and Quantitative Analyses of Glycosides with Aglycons as Aroma Compounds. Journal of Agricultural and Food Chemistry, 48, 5411-5418. [Google Scholar] [CrossRef] [PubMed]
[33] Mitsui, K., David, F., Dumont, E., Ochiai, N., Tamura, H. and Sandra, P. (2015) LC Fractionation Followed by Pyrolysis GC-MS for the in-Depth Study of Aroma Compounds Formed during Tobacco Combustion. Journal of Analytical and Applied Pyrolysis, 116, 68-74. [Google Scholar] [CrossRef
[34] 王燕, 刘志华, 刘春波, 陈永宽, 蒋丽红, 王亚明. 烟草中两种紫罗兰醇葡萄糖苷衍生物的分离鉴定及热分析研究[J]. 分析测试学报, 2012, 31(1): 22-28.
[35] Shen, D.K. and Gu, S. (2009) The Mechanism for Thermal Decomposition of Cellulose and Its Main Products. Bioresource Technology, 100, 6496-6504. [Google Scholar] [CrossRef] [PubMed]
[36] Carmines, E.L. and Gaworski, C.L. (2005) Toxicological Evaluation of Glycerin as a Cigarette Ingredient. Food and Chemical Toxicology, 43, 1521-1539. [Google Scholar] [CrossRef] [PubMed]
[37] Gómez-Siurana, A., Marcilla, A., Beltrán, M., Berenguer, D., Mar-tínez-Castellanos, I., Catalá, L. and Menargues, S. (2014) TGA/FTIR Study of the MCM-41-Catalytic Pyrolysis of To-bacco and Tobacco—Glycerol Mixtures. Thermochimica Acta, 587, 24-32. [Google Scholar] [CrossRef
[38] 谢剑平, 赵明月, 吴鸣, 赵晓东, 王昇, 谢复炜. 白肋烟重要香味物质组成的研究[J]. 烟草科技, 2002(10): 3-16.
[39] 霍现宽, 刘珊, 崔凯, 唐培培, 曾世通, 孙世豪, 宗永立. 加热状态下烟草烟气香味成分释放特征[J]. 烟草科技, 2017, 50(8): 37-45.