过渡金属催化砜的脱硫交叉偶联反应的研究进展
Research Progress in Transition Metal Catalyzed Desulfurization Cross-Coupling Reactions of Sulfone
DOI: 10.12677/AAC.2023.132024, PDF,   
作者: 段璐琼, 黄晓雷*：浙江师范大学化学与材料科学学院，浙江 金华
关键词: 过渡金属催化；有机砜；脱硫；交叉偶联；Transition Metal-Catalysis； Sulfones； Desulfurization； Cross-Coupling
摘要: 近年来，有机砜作为新型交叉偶联试剂在过渡金属催化反应中的应用成为有机合成领域的研究热点。将砜试剂作为新型偶联底物，可以避免底物的预活化，而且砜基官能团易在温和的条件下引入和脱除，对各种官能团容忍性较好，在有机合成领域具有极高的应用价值。本文主要对近年来不同金属催化的砜的脱硫交叉偶联反应相关研究进行了综述。
Abstract: In recent years, the application of organic sulfones as novel cross coupling reagents in transition metal catalyzed reactions has become a research hotspot in the field of organic synthesis. Using sulfone reagents as a novel coupling substrate can avoid the pre activation of the substrate, and sulfonyl functional groups can be easily introduced and removed under mild conditions, with good tolerance for various functional groups, which has high application value in the field of organic synthesis. This article mainly reviews the recent studies on the desulfurization cross coupling reactions of sulfone catalyzed by different metals.
文章引用：段璐琼, 黄晓雷. 过渡金属催化砜的脱硫交叉偶联反应的研究进展[J]. 分析化学进展, 2023, 13(2): 203-215. https://doi.org/10.12677/AAC.2023.132024

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