稀土掺杂下外延HfO2薄膜的铁电性研究
Ferroelectric Properties of Rare Earth-Doped Epitaxial HfO2 Thin Films
DOI: 10.12677/app.2024.148063, PDF,   
作者: 刘 洋*, 李伟伟:南京航空航天大学物理学院,江苏 南京
关键词: HfO2薄膜稀土掺杂铁电薄膜HfO2 Film Rare Earth-Doped Ferroelectric Film
摘要: 本研究专注于稀土金属Y和La掺下HfO2薄膜的铁电性。采用脉冲激光沉积技术,在(001)取向SrTiO3衬底上利用La0.7Sr0.3MnO3薄膜作为底电极,成功实现了沿(111)取向生长的外延薄膜。研究发现,掺杂下的HfO2薄膜呈现出较好的结晶性,在室温下压电系数d33约为6 pm/V,畴翻转可达180˚,剩余极化强度可达到12.91 μC/cm2,表现出良好的铁电性。这些实验成果为基于HfO2薄膜的电子器件设计提供了重要的实验基础。
Abstract: This study focuses on the ferroelectric properties of Y and La doped HfO2 thin films. The epitaxial films grown along the (111) orientation were successfully prepared on (001)-oriented SrTiO3 substrate using La0.7Sr0.3MnO3 film as the substrate electrode by Pulsed laser deposition technique. The results show that the doped HfO2 films exhibit good crystallinity, the piezoelectric coefficient d33 is about 6 pm/V at room temperature, the domain inversion can reach 180˚, and the residual polarization strength can reach 12.91 μC/cm2, exhibit good ferroelectric properties. These experimental results provide an important experimental basis for the design of electronic devices based on HfO2 thin films.
文章引用:刘洋, 李伟伟. 稀土掺杂下外延HfO2薄膜的铁电性研究[J]. 应用物理, 2024, 14(8): 595-600. https://doi.org/10.12677/app.2024.148063

参考文献

[1] Xue, S. (2021) Overview of Computer Architecture Development Direction Breaking through Von Neumann Architecture. International Core Journal of Engineering, 7, 330-334.
[2] Troiler-McKinstry, S. (2020) Impact of Ferroelectricity. American Ceramic Society Bulletin, 99, 22-23.
[3] Chen, H., Zhou, X., Tang, L., Chen, Y., Luo, H., Yuan, X., et al. (2022) HfO2-Based Ferroelectrics: From Enhancing Performance, Material Design, to Applications. Applied Physics Reviews, 9, Article 011307. [Google Scholar] [CrossRef
[4] Sharma, D.K., Khosla, R. and Sharma, S.K. (2015) Multilevel Metal/Pb(Zr0.52Ti0.48)O3/TiOxNy/Si for Next Generation Feram Technology Node. Solid-State Electronics, 111, 42-46. [Google Scholar] [CrossRef
[5] Kohlstedt, H., Mustafa, Y., Gerber, A., Petraru, A., Fitsilis, M., Meyer, R., et al. (2005) Current Status and Challenges of Ferroelectric Memory Devices. Microelectronic Engineering, 80, 296-304. [Google Scholar] [CrossRef
[6] Le, H.V., Takahashi, M. and Sakai, S. (2011) Downsizing of Ferroelectric-Gate Field-Effect-Transistors for Ferroelectric-NAND Flash Memory Cells. Proceedings of 2011 3rd IEEE International Memory Workshop (IMW), Monterey, CA, USA, 22-25 May 2011, 1-4.
[7] Böscke, T.S., Müller, J., Bräuhaus, D., Schröder, U. and Böttger, U. (2011) Ferroelectricity in Hafnium Oxide Thin Films. Applied Physics Letters, 99, Article 102903. [Google Scholar] [CrossRef
[8] Bousquet, E., Spaldin, N.A. and Ghosez, P. (2010) Strain-Induced Ferroelectricity in Simple Rocksalt Binary Oxides. Physical Review Letters, 104, Article 037601. [Google Scholar] [CrossRef] [PubMed]
[9] Park, M.H., Schenk, T. and Schroeder, U. (2019) Dopants in Atomic Layer Deposited HfO2 Thin Films. In: Schroeder, U., Hwang, C.S. and Funakubo, H., Eds., Ferroelectricity in Doped Hafnium Oxide: Materials, Properties and Devices, Elsevier, 49-74. [Google Scholar] [CrossRef
[10] Batra, R., Huan, T.D., Jones, J.L., Rossetti, G. and Ramprasad, R. (2017) Factors Favoring Ferroelectricity in Hafnia: A First-Principles Computational Study. The Journal of Physical Chemistry C, 121, 4139-4145. [Google Scholar] [CrossRef
[11] 袁国亮, 王琛皓, 唐文彬, 等, HfO2基铁电薄膜的结构、性能调控及典型器件应用[J]. 物理学报, 2023, 72(9): 241-262.
[12] Howard, C.J., Kisi, E.H., Roberts, R.B. and Hill, R.J. (1990) Neutron Diffraction Studies of Phase Transformations between Tetragonal and Orthorhombic Zirconia in Magnesia-Partially-Stabilized Zirconia. Journal of the American Ceramic Society, 73, 2828-2833. [Google Scholar] [CrossRef
[13] Fina, I. and Sánchez, F. (2021) Epitaxial Ferroelectric HfO2 Films: Growth, Properties, and Devices. ACS Applied Electronic Materials, 3, 1530-1549. [Google Scholar] [CrossRef
[14] Muller, J., Polakowski, P., Riedel, S., Mueller, S., Yurchuk, E. and Mikolajick, T. (2014) Ferroelectric Hafnium Oxide a Game Changer to FRAM? 2014 14th Annual Non-Volatile Memory Technology Symposium (NVMTS), Jeju, 27-29 October 2014, 1-7. [Google Scholar] [CrossRef
[15] Katayama, K., Shimizu, T., Sakata, O., Shiraishi, T., Nakamura, S., Kiguchi, T., et al. (2016) Growth of (111)-Oriented Epitaxial and Textured Ferroelectric Y-Doped HfO2 Films for Downscaled Devices. Applied Physics Letters, 109, Article No. 112901. [Google Scholar] [CrossRef
[16] Oh, I., Kim, M., Lee, J., Lee, C., Lansalot-Matras, C., Noh, W., et al. (2013) The Effect of La2O3-Incorporation in HfO2 Dielectrics on Ge Substrate by Atomic Layer Deposition. Applied Surface Science, 287, 349-354. [Google Scholar] [CrossRef
[17] Mueller, S., Mueller, J., Singh, A., Riedel, S., Sundqvist, J., Schroeder, U., et al. (2012) Incipient Ferroelectricity in Al-Doped HfO2 Thin Films. Advanced Functional Materials, 22, 2412-2417. [Google Scholar] [CrossRef
[18] Zhang, Y., Fan, Z., Wang, D., Wang, J., Zou, Z., Li, Y., et al. (2020) Enhanced Ferroelectric Properties and Insulator—Metal Transition-Induced Shift of Polarization-Voltage Hysteresis Loop in VOX-Capped Hf0.5Zr0.5O2 Thin Films. ACS Applied Materials & Interfaces, 12, 40510-40517. [Google Scholar] [CrossRef] [PubMed]
[19] Cheema, S.S., Kwon, D., Shanker, N., dos Reis, R., Hsu, S., Xiao, J., et al. (2020) Enhanced Ferroelectricity in Ultrathin Films Grown Directly on Silicon. Nature, 580, 478-482. [Google Scholar] [CrossRef] [PubMed]
[20] 祝祺, 杨浩. 外延生长的菱方相Hf0.5Zr0.5O2薄膜的铁电性[J]. 应用物理, 2022, 12(1): 1-7.
[21] Yun, Y., Buragohain, P., Li, M., Ahmadi, Z., Zhang, Y., Li, X., et al. (2022) Intrinsic Ferroelectricity in Y-Doped HfO2 Thin Films. Nature Materials, 21, 903-909. [Google Scholar] [CrossRef] [PubMed]
[22] Song, T., Tan, H., Bachelet, R., Saint-Girons, G., Fina, I. and Sánchez, F. (2021) Impact of La Concentration on Ferroelectricity of La-Doped HfO2 Epitaxial Thin Films. ACS Applied Electronic Materials, 3, 4809-4816. [Google Scholar] [CrossRef] [PubMed]
[23] 李敏, 时鑫娜, 张泽霖, 吉彦达, 樊济宇, 杨浩. 柔性Pb(Zr0.53Ti0.47)O3薄膜的高温铁电特性[J]. 物理学报, 2019, 68(8): 223-228.
[24] Lyu, J., Fina, I., Solanas, R., Fontcuberta, J. and Sánchez, F. (2019) Growth Window of Ferroelectric Epitaxial Hf0.5Zr0.5O2 Thin Films. ACS Applied Electronic Materials, 1, 220-228. [Google Scholar] [CrossRef
[25] Chernikova, A., Kozodaev, M., Markeev, A., Negrov, D., Spiridonov, M., Zarubin, S., et al. (2016) Ultrathin Hf0.5Zr0.5O2 Ferroelectric Films on Si. ACS Applied Materials & Interfaces, 8, 7232-7237. [Google Scholar] [CrossRef] [PubMed]