玉龙高铁铜精矿常压酸浸液选择性萃铜工艺研究
Study on Selective Copper Extraction Process from Atmospheric Acid Leaching Solution of Yulong High Iron Copper Concentrate
DOI: 10.12677/meng.2024.113019, PDF,   
作者: 刘 春:福州大学化工学院,福建 福州;紫金矿业集团股份有限公司,福建 上杭
关键词: 玉龙铜矿常压酸浸液溶解萃取Yulong Copper Mine Atmospheric Acid Leaching Solution Solvent Extraction Copper
摘要: 以玉龙高铁铜精矿常压酸浸液为研究对象,通过萃取剂遴选及萃取性能对比试验,选择Mextral5640H作为最优萃取剂,通过两级逆流萃取,当有机相浓度为20%,萃取相比(O/A)为1.7:1时,铜铁分离系数达到2500,萃余液中铜离子浓度降至0.4 g/L,经过一级反萃可使富铜液中的铜离子浓度达到45 g/L,实现了玉龙高铁铜精矿常压酸浸液中铜的选择性高效提取。
Abstract: Taking the atmospheric acid leaching solution of Yulong high-iron copper concentrate as the research object, Mextral5640H was selected as the optimal extractant through the comparison test of extractant selection and extraction performance. Through two-stage countercurrent extraction, when the organic phase concentration was 20% and the extraction ratio (O/A) was 1.7:1, the copper-iron separation coefficient reached 2500, and the copper ion concentration in the raffinate was reduced to 0.4 g/L. After one-stage stripping, the copper ion concentration in the copper-rich liquid can reach 45 g/L. The selective and efficient extraction of copper from the atmospheric acid leaching solution of Yulong high-iron copper concentrate was realized.
文章引用:刘春. 玉龙高铁铜精矿常压酸浸液选择性萃铜工艺研究[J]. 冶金工程, 2024, 11(3): 153-162. https://doi.org/10.12677/meng.2024.113019

参考文献

[1] 段大源, 徐文隆, 次成塔西, 等. 西藏某氧化铜矿湿法冶炼工艺优化[J]. 世界有色金属, 2022(22): 18-20.
[2] 张永德, 李皊值, 阮仁满. 黄铜矿的湿法冶金工艺研究进展[J]. 稀有金属, 2005, 29(1): 83-87.
[3] Bobozoda, S., Boboev, I.R. and Strizhko, L.S. (2017) Gold and Copper Recovery from Flotation Concentrates of Tarror Deposit by Autoclave Leaching. Journal of Mining Science, 53, 352-357. [Google Scholar] [CrossRef
[4] 刘大星. 湿法炼铜的发展与前景[J]. 资源再生, 2005(7): 34-36.
[5] 李明凤, 段焕春, 严茂文, 等. 湿法冶金技术在滇中铜矿石处理中的应用[J]. 湿法冶金, 2006, 25(3): 117-119.
[6] 郭亚惠. 铜湿法冶金现状及未来发展方向[J]. 中国有色冶金, 2006, 35(4): 1-6.
[7] 蒋学先, 贾喜君, 何贵香. 铜的湿法冶金现状及展望[J]. 金属材料与冶金工程, 2007, 35(5): 61-64.
[8] 李鹏程, 王晓鸽, 张文娟. TXIB对Mextral973H从铜氨溶液中萃取铜及氨的影响研究[J]. 有色金属(冶炼部分), 2019, 3(3): 6-10.
[9] Soeezi, A., Haghshenas-Kashani, B., Farahmand, F. and Osanloo, A. (2022) Extraction of Co, Ni and Cu by the Solvent Extraction Method with Simulation Setup for Control, Alarm and Protection System. Canadian Metallurgical Quarterly, 61, 33-47. [Google Scholar] [CrossRef
[10] 阳启华, 邹潜, 汤启明, 等. 从铜铁浸出液中选择性萃取铜试验研究[J]. 湿法冶金, 2017, 36(4): 293-296.
[11] 李衍林, 世仙果, 李兴彬, 等. 从湿法炼锌浸出液中选择性萃取分离回收铜[J]. 有色金属工程, 2021, 11(6): 43-48.
[12] Chen, X., Xu, B., Zhou, T., Liu, D., Hu, H. and Fan, S. (2015) Separation and Recovery of Metal Values from Leaching Liquor of Mixed-Type of Spent Lithium-Ion Batteries. Separation and Purification Technology, 144, 197-205. [Google Scholar] [CrossRef
[13] Hosseinzadeh, M., Petersen, J. and Azizi, A. (2022) Solvent Extraction Studies of Copper from a Heap Leach Liquor Using Mextral 5640H. Minerals, 12, Article 1322. [Google Scholar] [CrossRef
[14] He, Y., Zhang, Y., Huang, J., Zheng, Q. and Liu, H. (2022) Extraction of Vanadium(V) from a Vanadium-Bearing Shale Leachate through Bifunctional Coordination in Mextral 984H Extraction System. Separation and Purification Technology, 288, Article 120452. [Google Scholar] [CrossRef
[15] Li, X., Ai, X., He, L., Ji, S., Hu, M., Ding, J., et al. (2017) Solvent Extraction Separate of Zinc and Cadmium from Magnesium and Calcium in Sulfuric Acid Medium by Mixing Extractants. Journal of Central South University, 24, 2253-2259. [Google Scholar] [CrossRef
[16] Agarwal, S., Ferreira, A.E., Santos, S.M.C., Reis, M.T.A., Ismael, M.R.C., Correia, M.J.N., et al. (2010) Separation and Recovery of Copper from Zinc Leach Liquor by Solvent Extraction Using Acorga M5640. International Journal of Mineral Processing, 97, 85-91. [Google Scholar] [CrossRef
[17] Shakibania, S., Mokmeli, M. and Manafi, Z. (2022) Incorporation of Chloride Ion in a Copper Solvent Extraction Process: A Thermodynamic View. Minerals Engineering, 187, Article 107758. [Google Scholar] [CrossRef