离子辐照能量对石墨烯界面热输运的调控
Modulating Thermal Transport across Graphene Interface with Ion Irradiation Energy
DOI: 10.12677/ms.2024.1410158, PDF,   
作者: 王 群, 区炳显, 杨永强, 刘 峥：江苏省特种设备安全监督检验研究院无锡分院，江苏 无锡；朱 楠, 赵 宇*：南京工程学院工程训练中心应用技术学院，江苏 南京
关键词: 石墨烯；离子辐照；界面热导；晶格结构；吸附作用；Graphene； Ion irradiation； Interfacial Thermal Conductance； Lattice Structure； Adsorption Interaction
摘要: 作为一种二维材料，石墨烯因其超高的导热系数而被广泛研究，特别是在电子器件散热领域。然而，石墨烯界面的低热导限制了石墨烯在散热领域中应用。为了提高石墨烯界面的热传导效率，文章通过聚焦镓离子束对石墨烯进行离子辐照，研究了离子辐照能量对石墨烯界面热输运的影响。实验测量结果显示，随着离子辐照能量的增加，Al/graphene/SiO2的界面热导呈现上升的趋势，并且在30 kV能量下升高了近3倍。实验表征及理论计算结果显示，镓离子辐照破坏了石墨烯原有的晶格结构，导致离子辐照石墨烯表面上的C/O化学官能团发生了重构，提高了铝膜与离子辐照石墨烯之间界面的吸附作用，进而增加了界面上的声子透射率，最终提升了Al/graphene/SiO2的界面热导。
Abstract: As a two-dimensional material, graphene has been widely studied for its ultra-high thermal conductivity, especially in the field of electronic device cooling. However, the high thermal resistance at the graphene interface limits the application of graphene in the field of heat dissipation. In order to improve the heat conduction efficiency of graphene interface, the effects of energy of ion irradiation on the thermal transport across the graphene interface are investigated in this paper after graphene irradiated by focusing gallium ion beams. It is demonstrated that the interfacial thermal conductance of Al/graphene/SiO2 shows an upward trend with increasing energy and increases up to nearly 3 times at the energy of 30 kV. The experimental characterization and theoretical calculation results show that Ga ion irradiation destroys the original lattice structure of graphene, leading to the reconstruction of C/O chemical functional groups on the ion-irradiated graphene surface, which intensifies the adsorption strength between Al film and ion-irradiated graphene. The increased interfacial adsorption strength is beneficial to more phonons being able to transport across the interface, and finally leads to the increased thermal conductance of Al/graphene/SiO2.
文章引用：王群, 区炳显, 杨永强, 刘峥, 朱楠, 赵宇. 离子辐照能量对石墨烯界面热输运的调控[J]. 材料科学, 2024, 14(10): 1446-1454. https://doi.org/10.12677/ms.2024.1410158

参考文献

[1] Lee, C., Wei, X., Kysar, J.W. and Hone, J. (2008) Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene. Science, 321, 385-388. [Google Scholar] [CrossRef] [PubMed]
[2] Hao, F., Fang, D. and Xu, Z. (2011) Mechanical and Thermal Transport Properties of Graphene with Defects. Applied Physics Letters, 99, Article 041901. [Google Scholar] [CrossRef] 
[3] Novoselov, K.S., Geim, A.K., Morozov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., et al. (2004) Electric Field Effect in Atomically Thin Carbon Films. Science, 306, 666-669. [Google Scholar] [CrossRef] [PubMed]
[4] Wang, F., Zhang, Y., Tian, C., Girit, C., Zettl, A., Crommie, M., et al. (2008) Gate-Variable Optical Transitions in Graphene. Science, 320, 206-209. [Google Scholar] [CrossRef] [PubMed]
[5] Nair, R.R., Blake, P., Grigorenko, A.N., Novoselov, K.S., Booth, T.J., Stauber, T., et al. (2008) Fine Structure Constant Defines Visual Transparency of Graphene. Science, 320, 1308-1308. [Google Scholar] [CrossRef] [PubMed]
[6] Bonaccorso, F., Sun, Z., Hasan, T. and Ferrari, A.C. (2010) Graphene Photonics and Optoelectronics. Nature Photonics, 4, 611-622. [Google Scholar] [CrossRef] 
[7] Balandin, A.A., Ghosh, S., Bao, W., Calizo, I., Teweldebrhan, D., Miao, F., et al. (2008) Superior Thermal Conductivity of Single-Layer Graphene. Nano Letters, 8, 902-907. [Google Scholar] [CrossRef] [PubMed]
[8] Cai, W., Moore, A.L., Zhu, Y., Li, X., Chen, S., Shi, L., et al. (2010) Thermal Transport in Suspended and Supported Monolayer Graphene Grown by Chemical Vapor Deposition. Nano Letters, 10, 1645-1651. [Google Scholar] [CrossRef] [PubMed]
[9] Hopkins, P.E., Baraket, M., Barnat, E.V., Beechem, T.E., Kearney, S.P., Duda, J.C., et al. (2012) Manipulating Thermal Conductance at Metal-Graphene Contacts via Chemical Functionalization. Nano Letters, 12, 590-595. [Google Scholar] [CrossRef] [PubMed]
[10] Foley, B.M., Hernández, S.C., Duda, J.C., Robinson, J.T., Walton, S.G. and Hopkins, P.E. (2015) Modifying Surface Energy of Graphene via Plasma-Based Chemical Functionalization to Tune Thermal and Electrical Transport at Metal Interfaces. Nano Letters, 15, 4876-4882. [Google Scholar] [CrossRef] [PubMed]
[11] Jiang, T., Zhang, X., Vishwanath, S., Mu, X., Kanzyuba, V., Sokolov, D.A., et al. (2016) Covalent Bonding Modulated Graphene-Metal Interfacial Thermal Transport. Nanoscale, 8, 10993-11001. [Google Scholar] [CrossRef] [PubMed]
[12] Han, H., Zhang, Y., Wang, N., Samani, M.K., Ni, Y., Mijbil, Z.Y., et al. (2016) Functionalization Mediates Heat Transport in Graphene Nanoflakes. Nature Communications, 7, Article No. 11281. [Google Scholar] [CrossRef] [PubMed]
[13] Koh, Y.K., Bae, M., Cahill, D.G. and Pop, E. (2010) Heat Conduction across Monolayer and Few-Layer Graphenes. Nano Letters, 10, 4363-4368. [Google Scholar] [CrossRef] [PubMed]
[14] Walton, S.G., Foley, B.M., Hernández, S.C., Boris, D.R., Baraket, M., Duda, J.C., et al. (2017) Plasma-Based Chemical Functionalization of Graphene to Control the Thermal Transport at Graphene-Metal Interfaces. Surface and Coatings Technology, 314, 148-154. [Google Scholar] [CrossRef] 
[15] Wejrzanowski, T., Grybczuk, M., Wasiluk, M. and Kurzydlowski, K.J. (2015) Heat Transfer through Metal-Graphene Interfaces. AIP Advances, 5, Article 077142. [Google Scholar] [CrossRef] 
[16] Chen, L., Huang, Z. and Kumar, S. (2013) Phonon Transmission and Thermal Conductance across Graphene/Cu Interface. Applied Physics Letters, 103, Article 123110. [Google Scholar] [CrossRef] 
[17] Chen, L., Huang, Z. and Kumar, S. (2014) Impact of Bonding at Multi-Layer Graphene/Metal Interfaces on Thermal Boundary Conductance. RSC Advances, 4, 35852-35861. [Google Scholar] [CrossRef] 
[18] Mao, R., Kong, B.D., Gong, C., Xu, S., Jayasekera, T., Cho, K., et al. (2013) First-Principles Calculation of Thermal Transport in Metal/Graphene Systems. Physical Review B, 87, Article 165410. [Google Scholar] [CrossRef] 
[19] Tao, Y., Wu, C., Qi, H., Liu, C., Wu, X., Hao, M., et al. (2020) The Enhancement of Heat Conduction across the Metal/Graphite Interface Treated with a Focused Ion Beam. Nanoscale, 12, 14838-14846. [Google Scholar] [CrossRef] [PubMed]
[20] Malard, L.M., Pimenta, M.A., Dresselhaus, G. and Dresselhaus, M.S. (2009) Raman Spectroscopy in Graphene. Physics Reports, 473, 51-87. [Google Scholar] [CrossRef] 
[21] Ferrari, A.C. and Robertson, J. (2000) Interpretation of Raman Spectra of Disordered and Amorphous Carbon. Physical Review B, 61, 14095-14107. [Google Scholar] [CrossRef] 
[22] Zhou, Y., Liao, Z., Wang, Y., Duesberg, G.S., Xu, J., Fu, Q., et al. (2010) Ion Irradiation Induced Structural and Electrical Transition in Graphene. The Journal of Chemical Physics, 133, Article 234703. [Google Scholar] [CrossRef] [PubMed]
[23] Wang, Q., Mao, W., Ge, D., Zhang, Y., Shao, Y. and Ren, N. (2013) Effects of Ga Ion-Beam Irradiation on Monolayer Graphene. Applied Physics Letters, 103, Article 073501. [Google Scholar] [CrossRef] 
[24] Wang, Q., Shao, Y., Ge, D., Yang, Q. and Ren, N. (2015) Surface Modification of Multilayer Graphene Using Ga Ion Irradiation. Journal of Applied Physics, 117, Article 165303. [Google Scholar] [CrossRef] 
[25] Al-Harthi, S.H., Elzain, M., Al-Barwani, M., Kora'a, A., Hysen, T., Myint, M.T.Z., et al. (2012) Unusual Surface and Edge Morphologies, Sp2 to Sp3 Hybridized Transformation and Electronic Damage after Ar+ Ion Irradiation of Few-Layer Graphene Surfaces. Nanoscale Research Letters, 7, 1-11. [Google Scholar] [CrossRef] [PubMed]
[26] Lu, J., Bao, Y., Su, C.L. and Loh, K.P. (2013) Properties of Strained Structures and Topological Defects in Graphene. ACS Nano, 7, 8350-8357. [Google Scholar] [CrossRef] [PubMed]

为你推荐